Department of Polymer Science and Engineering., Busan, 46241, Korea.
Chem Rec. 2018 Jul;18(7-8):759-775. doi: 10.1002/tcr.201700030. Epub 2017 Aug 17.
Organic/inorganic hybrid nanocomposites, in particular polymer based hybrid nanocomposites, constitute emerging advanced materials since they combine unique properties from the inorganic and organic (i. e. polymeric) components. We investigated three different hybrid nanocomposites depending on dimensions of the dispersed phase in the nanometer range,; polymer-layered silicate (PLS) nanocomposites where polymers are mixed with layered silicates, polymer/graphene oxide hybrid nanocomposites, and polymer hybrid nanocomposites with reinforcing polymers with isodimensional phases of inorganic silicas using sol-gel reactions. This Accounts reports the chronological progress of our landmark results on the polymer based hybrid nanocomposites of the three characteristic types that have been prepared in my laboratory for more than two decades, with their impacts, importance and advanced application of the related research fields for readers.
有机/无机杂化纳米复合材料,特别是基于聚合物的杂化纳米复合材料,是一种新兴的先进材料,因为它们结合了无机和有机(即聚合物)成分的独特性质。我们研究了三种不同的杂化纳米复合材料,根据分散相在纳米范围内的尺寸而定,分别是聚合物层状硅酸盐(PLS)纳米复合材料,其中聚合物与层状硅酸盐混合;聚合物/氧化石墨烯杂化纳米复合材料;以及使用溶胶-凝胶反应制备的具有等尺寸无机硅相的增强聚合物的聚合物杂化纳米复合材料。本报告按时间顺序介绍了我们在实验室二十多年来制备的三种典型类型的基于聚合物的杂化纳米复合材料的标志性成果,以及它们对相关研究领域的影响、重要性和先进应用,供读者参考。