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用于心血管应用的 NiTi 形状记忆合金上制备的混合 a-CNH+TiO+TiN 型表面层。

Hybrid a-CNH+TiO+TiN-type surface layers produced on NiTi shape memory alloy for cardiovascular applications.

机构信息

Faculty of Materials Science & Engineering, Warsaw University of Technology, Warsaw, Poland.

Pathology Department, Children's Memorial Health Institute, Warsaw, Poland.

出版信息

Nanomedicine (Lond). 2017 Sep;12(18):2233-2244. doi: 10.2217/nnm-2017-0092. Epub 2017 Aug 18.

Abstract

AIM

The goal was to improve the properties of NiTi shape memory alloy to make it suitable for cardiac applications. For this purpose, a hybrid a-CNH+TiO+TiN-type surface layer was produced on NiTi alloy and characterized.

MATERIALS & METHODS: The NiTi alloy subjected to hybrid process combining low-temperature oxynitriding under glow discharge conditions and radio frequency chemical vapor deposition process was examined for microstructure, surface topography, corrosion resistance, wettability and surface-free energy, Ni ion release and platelets adhesion, aggregation and activation.

RESULTS

The hybrid surface layers showed slightly increased surface roughness, better corrosion resistance, a more hydrophobic nature, decreased surface free energy, smaller release of nickel ions and reduced platelets activation.

CONCLUSION

The produced layers could expand the range of NiTi medical applications.

摘要

目的

旨在改善 NiTi 形状记忆合金的性能使其适用于心脏应用。为此,在 NiTi 合金上制备了混合 a-CNH+TiO+TiN 型表面层,并对其进行了表征。

材料与方法

对经辉光放电条件下低温氧氮化与射频化学气相沉积工艺相结合的复合处理的 NiTi 合金进行了微观结构、表面形貌、耐腐蚀性、润湿性和表面自由能、Ni 离子释放和血小板黏附、聚集和激活的研究。

结果

复合表面层的表面粗糙度略有增加,耐腐蚀性更好,疏水性更强,表面自由能降低,Ni 离子释放和血小板激活减少。

结论

所制备的涂层可扩大 NiTi 医用材料的应用范围。

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