School of Chemistry, University of Manchester , Oxford Rd, Manchester M13 9PL, U.K.
J Org Chem. 2017 Nov 17;82(22):11933-11938. doi: 10.1021/acs.joc.7b01778. Epub 2017 Sep 7.
A one-pot domino N-arylation protocol is described using diaryliodonium reagents under copper catalysis. The reaction uses both aryl groups of the diaryliodonium reagent to generate triarylamines starting from simple anilines, representing an atom-economical preparation of an important class of organic material building blocks.
本文描述了一种在铜催化下使用二芳基碘鎓试剂一锅多米诺 N-芳基化反应。该反应利用二芳基碘鎓试剂的两个芳基基团，从简单苯胺出发生成三芳基胺，代表了一类重要的有机材料砌块的原子经济性制备方法。
