铜催化的苯酚和二芳基醚衍生物的合成——二芳基碘鎓盐的羟基化反应
Copper-catalyzed synthesis of phenol and diaryl ether derivatives hydroxylation of diaryliodoniums.
作者信息
Ye Lianbao, Han Chao, Shi Peiqi, Gao Wei, Mei Wenjie
机构信息
School of Pharmacy, Guangdong Pharmaceutical University Guangzhou 510006 Guangdong China
Guangdong Province Engineering Technology Center for Molecular Probes & Biomedical Imaging, Guangdong Pharmaceutical University Guangzhou 510006 Guangdong China.
出版信息
RSC Adv. 2019 Jul 10;9(37):21525-21529. doi: 10.1039/c9ra04282b. eCollection 2019 Jul 5.
A copper-catalysed hydroxylation of diaryliodoniums to generate phenols and diaryl ethers is reported. This method allows the synthesis of diversely functionalized phenols under mild reaction conditions without the need for a strong inorganic base or an expensive noble-metal catalyst. Significantly, convenient application of diaryliodoniums is demonstrated in the preparation of diaryl ethers in a one-pot operation.
据报道，一种铜催化的二芳基碘鎓盐羟基化反应可生成酚类和二芳基醚。该方法能够在温和的反应条件下合成多种功能化的酚类，无需强碱或昂贵的贵金属催化剂。值得注意的是，二芳基碘鎓盐在一锅法制备二芳基醚中展现出便捷的应用。
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