SZU-NUS Collaborative Innovation Center for Optoelectronic Science and Technology and Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province, College of Optoelectronic Engineering, Shenzhen University, Shenzhen 518060, P. R. China.
Nanoscale. 2017 Sep 21;9(36):13384-13403. doi: 10.1039/c7nr03318d.
Recently, a new two-dimensional material, single- or few-layered black phosphorus (BP), has attracted considerable attention for applications in electronics, optoelectronics, and batteries due to its unique properties, including large specific surface area, anisotropy, and tunable and direct band gaps. In particular, contributions to electrochemical energy storage devices, such as lithium and sodium ion batteries and supercapacitors, have emerged. However, critical issues remain to be explored before scaled-up commercial production of BP, such as preparation, stability, and performance. Herein, we present the first review of recent progress in BP-based electrochemical energy storage device. The preparation and electrochemical properties of black phosphorus, recent advances, potential challenges, and relevant perspectives in electrochemical energy storage, and the potential of BP are discussed in this work.
最近，一种新型二维材料——单层或少数层黑磷（BP），因其独特的性质，包括大比表面积、各向异性和可调谐直接带隙，在电子学、光电学和电池领域引起了相当大的关注。特别是，它在电化学储能器件，如锂离子和钠离子电池以及超级电容器等方面的应用已经出现。然而，在大规模商业化生产 BP 之前，仍有一些关键问题需要探索，如制备、稳定性和性能等。本文综述了基于 BP 的电化学储能器件的最新进展。讨论了黑磷的制备和电化学性能、近期进展、潜在挑战以及在电化学储能中的相关观点，以及 BP 的潜力。
