N²-吲哚基-1,2,3-三唑的荧光活性研究
Study on the Fluorescent Activity of N²-Indolyl-1,2,3-triazole.
作者信息
Zhang You-Can, Jin Rui, Li Luo-Yuan, Chen Zili, Fu Li-Min
机构信息
Department of Chemistry, Renmin University of China, Beijing 100872, China.
出版信息
Molecules. 2017 Sep 5;22(9):1380. doi: 10.3390/molecules22091380.
A new type of blue emitter, ²-Indolyl-1,2,3-triazoles (NITs), with the λ ranging from 420-480 nm and the Stokes shift from 89-143 nm, were synthesized through the coupling reaction of indoles with triazole derivatives. The influence of different substitution patterns on the optical properties (efficiency, excitation, and emission wavelengths) of the NITs was investigated. In addition, one palladium complex were synthesized by using NITs as the ligands, which, however, exhibited no fluorescent activity, but did show the enhanced co-planarity. Lastly, two bio-active molecule derivatives were explored for the potential use of these novel dyes in related chemical and biological applications.
一种新型蓝色发光体，即²-吲哚基-1,2,3-三唑（NITs），其波长范围为420 - 480纳米，斯托克斯位移为89 - 143纳米，通过吲哚与三唑衍生物的偶联反应合成。研究了不同取代模式对NITs光学性质（效率、激发和发射波长）的影响。此外，以NITs为配体合成了一种钯配合物，然而，该配合物没有荧光活性，但显示出增强的共平面性。最后，探索了两种生物活性分子衍生物，以研究这些新型染料在相关化学和生物学应用中的潜在用途。
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