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聚合物-介孔二氧化硅纳米复合材料的合成

Synthesis of Polymer-Mesoporous Silica Nanocomposites.

作者信息

Wei Liangming, Hu Nantao, Zhang Yafei

机构信息

National Key Laboratory of Nano/Micro Fabrication Technology, Key Laboratory for Thin Film and Microfabrication of Ministry of Education, Institute of Micro and Nano Science and Technology, Shanghai Jiao Tong University, Dongchuan Road, Shanghai, China.

出版信息

Materials (Basel). 2010 Jul 13;3(7):4066-4079. doi: 10.3390/ma3074066.

DOI:10.3390/ma3074066
PMID:28883321
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5445796/
Abstract

Polymer nanocomposites show unique properties combining the advantages of the inorganic nanofillers and the organic polymers. The mesoporous silica nanofillers have received much attention due to their ordered structure, high surface area and ease for functionalization of the nanopores. To accommodate macromolecules, the nanopores lead to unusually intimate interactions between the polymer and the inorganic phase, and some unusual properties can be observed, when compared with nonporous fillers. Whereas many review articles have been devoted to polymer/nonporous nanofiller nanocomposites, few review articles focus on polymer/mesoporous silica nanocomposites. This review summarizes the recent development in the methods for synthesizing polymer/mesoporous silica nanocomposites based on the papers published from 1998 to 2009, and some unique properties of these composites are also described.

摘要

聚合物纳米复合材料结合了无机纳米填料和有机聚合物的优点，展现出独特的性能。介孔二氧化硅纳米填料因其有序结构、高比表面积以及纳米孔易于功能化而备受关注。为了容纳大分子，纳米孔导致聚合物与无机相之间产生异常紧密的相互作用，与无孔填料相比，可以观察到一些不寻常的性能。虽然许多综述文章致力于聚合物/无孔纳米填料纳米复合材料，但很少有综述文章关注聚合物/介孔二氧化硅纳米复合材料。本综述基于1998年至2009年发表的论文，总结了聚合物/介孔二氧化硅纳米复合材料合成方法的最新进展，并描述了这些复合材料的一些独特性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1feb/5445796/ad565ad7e70a/materials-03-04066-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1feb/5445796/118c175eb45e/materials-03-04066-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1feb/5445796/c0968180d7c5/materials-03-04066-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1feb/5445796/00e61c443539/materials-03-04066-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1feb/5445796/ad565ad7e70a/materials-03-04066-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1feb/5445796/118c175eb45e/materials-03-04066-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1feb/5445796/c0968180d7c5/materials-03-04066-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1feb/5445796/00e61c443539/materials-03-04066-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1feb/5445796/ad565ad7e70a/materials-03-04066-g004.jpg

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[6]
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[7]
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[8]
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[9]
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[10]
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本文引用的文献

[1]
Self-reinforced hybrid polyethylene/MCM-41 nanocomposites: in-situ polymerisation and effect of MCM-41 content on rigidity.

J Nanosci Nanotechnol. 2009-6

[2]
Mesoporous silica sphere-polysulfone mixed matrix membranes for gas separation.

Langmuir. 2009-5-19

[3]
Polymer/silica nanocomposites: preparation, characterization, properties, and applications.

Chem Rev. 2008-9

[4]
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Langmuir. 2007-1-2

[5]
Some novel polymeric nanocomposites.

Acc Chem Res. 2006-12

[6]
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J Phys Chem B. 2005-9-29

[7]
Silica-based mesoporous organic-inorganic hybrid materials.

Angew Chem Int Ed Engl. 2006-5-12

[8]
Highly polarized luminescence from optical quality films of a semiconducting polymer aligned within oriented mesoporous silica.

J Am Chem Soc. 2004-4-14

[9]
Gatekeeping layer effect: a poly(lactic acid)-coated mesoporous silica nanosphere-based fluorescence probe for detection of amino-containing neurotransmitters.

J Am Chem Soc. 2004-2-18

[10]
Electrospun MEH-PPV/SBA-15 composite nanofibers using a dual syringe method.

J Am Chem Soc. 2003-11-26

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