School of Biosystems Engineering and Food Science, Zhejiang University, 866 Yuhangtang Road, Hangzhou 310058, P.R. China.
Nanoscale. 2017 Sep 28;9(37):13864-13878. doi: 10.1039/c7nr03824k.
Terahertz (THz) technology has attracted great worldwide interest and novel high-intensity THz sources and plasmonics are two of the most active fields of recent research. Being situated between infrared light and microwave radiation, the absorption of THz rays in molecular and biomolecular systems is dominated by the excitation of intramolecular and intermolecular vibrations. This indicates that THz technology is an effective tool for sensing applications. However, the low sensitivity of free-space THz detection limits the sensing applications, which gives a great opportunity to metamaterials. Metamaterials are periodic artificial electromagnetic media structured with a size scale smaller than the wavelength of external stimuli. They present localized electric field enhancement and large values of quality factor (Q factor) and show high sensitivity to minor environment changes. In the present work, the mechanism of THz metamaterial sensing and dry sample and microfluidic sensing applications based on metamaterials are introduced. Moreover, new directions of THz metamaterial sensing advancement and introduction of two-dimensional materials and nanoparticles for future THz applications are summarized and discussed.
太赫兹(THz)技术引起了全世界的极大兴趣,新型高强度太赫兹源和等离子体是最近研究中最活跃的两个领域。THz 射线位于红外光和微波辐射之间,在分子和生物分子系统中,THz 射线的吸收主要由分子内和分子间振动的激发所主导。这表明太赫兹技术是一种用于传感应用的有效工具。然而,自由空间太赫兹检测的低灵敏度限制了传感应用,这为超材料提供了巨大的机会。超材料是一种周期性的人工电磁介质,其结构的尺寸小于外部刺激的波长。它们具有局部电场增强和大的品质因数(Q 因数)值,并对微小的环境变化表现出高灵敏度。在本工作中,介绍了太赫兹超材料传感的机制以及基于超材料的干样品和微流控传感应用。此外,还总结和讨论了太赫兹超材料传感的新进展方向以及二维材料和纳米颗粒在未来太赫兹应用中的引入。