Kerr Andrew, Hartlieb Matthias, Sanchis Joaquin, Smith Timothy, Perrier Sébastien
Department of Chemistry, The University of Warwick, Coventry CV4 7AL, UK.
Chem Commun (Camb). 2017 Oct 31;53(87):11901-11904. doi: 10.1039/c7cc07241d.
The combination of the reversible addition fragmentation chain transfer (RAFT) polymerization R-group grafting from approach and RAFT one-pot acrylamide multiblock methodology is used to synthesise complex bottle-brush architectures. This is demonstrated for block copolymer grafted side chains and the insertion of ungrafted blocks into the backbone to yield multi-segmented bottle-brushes.
将可逆加成-断裂链转移（RAFT）聚合的从R基团接枝方法与RAFT一锅法丙烯酰胺多嵌段方法相结合，用于合成复杂的瓶刷状结构。这在嵌段共聚物接枝侧链以及将未接枝的嵌段插入主链以生成多段瓶刷方面得到了证明。
