State Key Laboratory of Bioelectronics, School of Biological Science and Medical Engineering, Southeast University, Nanjing, 210096, China.
Adv Mater. 2017 Dec;29(46). doi: 10.1002/adma.201704569. Epub 2017 Oct 17.
As an important characteristic of many creatures, structural colors play a crucial role in the survival of organisms. Inspired by these features, an intelligent structural color material with a heterogeneous striped pattern and stimuli-responsivity by fast self-assembly of colloidal nanoparticles in capillaries with a certain diameter range are presented here. The width, spacing, color, and even combination of the structural color stripe patterns can be precisely tailored by adjusting the self-assembly parameters. Attractively, with the integration of a near-infrared (NIR) light responsive graphene hydrogel into the structural color stripe pattern, the materials are endowed with light-controlled reversible bending behavior with self-reporting color indication. It is demonstrated that the striped structural color materials can be used as NIR-light-triggered dynamic barcode labels for the anti-counterfeiting of different products. These features of the bioinspired structural color stripe pattern materials indicate their potential values for mimicking structural color organisms, which will find important applications in constructing intelligent sensors, anti-counterfeiting devices, and so on.
作为许多生物的重要特征之一,结构色在生物的生存中起着至关重要的作用。受这些特征的启发,本文提出了一种智能结构色材料,它通过在一定直径范围内的毛细管中胶体纳米粒子的快速自组装来呈现具有非均匀条纹图案和刺激响应性的特征。通过调整自组装参数,可以精确地调整结构色条纹图案的宽度、间距、颜色,甚至组合。引人注目的是,通过将近红外(NIR)光响应的石墨烯水凝胶集成到结构色条纹图案中,材料具有光控可逆弯曲行为,并具有自报告颜色指示。实验表明,这些条纹结构色材料可用作 NIR 光触发的动态条码标签,用于不同产品的防伪。这些仿生结构色条纹图案材料的特性表明了它们在模拟结构色生物方面的潜在价值,这将在构建智能传感器、防伪装置等方面找到重要的应用。