Morita Kohei, Takijiri Kohei, Sakai Ken, Ozawa Hironobu
Department of Chemistry, Faculty of Science, Kyushu University, Motooka 744, Nishi-ku, Fukuoka, 819-0395, Japan.
Dalton Trans. 2017 Nov 14;46(44):15181-15185. doi: 10.1039/c7dt03710d.
The onset potential for H production from neutral water (pH 7) catalyzed by a platinum(ii) porphyrin (PtP-py) modified TiO electrode positions very close to the standard water reduction potential (less than 50 mV). H production is driven by the conduction band edge potential of TiO at the PtP-py-modified TiO cathode.
由铂（II）卟啉（PtP-py）修饰的TiO电极催化中性水（pH 7）产生H₂的起始电位非常接近标准水还原电位（小于50 mV）。在PtP-py修饰的TiO阴极上，H₂的产生是由TiO的导带边缘电位驱动的。
