一种由二氧化钛导带边缘电位驱动的、用于从中性水中进行光电化学制氢的铂卟啉修饰二氧化钛电极。
A platinum porphyrin modified TiO electrode for photoelectrochemical hydrogen production from neutral water driven by the conduction band edge potential of TiO.
作者信息
Morita Kohei, Takijiri Kohei, Sakai Ken, Ozawa Hironobu
机构信息
Department of Chemistry, Faculty of Science, Kyushu University, Motooka 744, Nishi-ku, Fukuoka, 819-0395, Japan.
出版信息
Dalton Trans. 2017 Nov 14;46(44):15181-15185. doi: 10.1039/c7dt03710d.
PMID:29068012
Abstract
The onset potential for H production from neutral water (pH 7) catalyzed by a platinum(ii) porphyrin (PtP-py) modified TiO electrode positions very close to the standard water reduction potential (less than 50 mV). H production is driven by the conduction band edge potential of TiO at the PtP-py-modified TiO cathode.
摘要
由铂（II）卟啉（PtP-py）修饰的TiO电极催化中性水（pH 7）产生H₂的起始电位非常接近标准水还原电位（小于50 mV）。在PtP-py修饰的TiO阴极上，H₂的产生是由TiO的导带边缘电位驱动的。
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