• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

具有优异一氧化碳、甲烷及碘吸附性能的富氟多孔有机聚合物材料的可调孔隙率合成

Synthesis of tunable porosity of fluorine-enriched porous organic polymer materials with excellent CO, CH and iodine adsorption.

作者信息

Li Guoyan, Yao Chan, Wang Jiku, Xu Yanhong

机构信息

Key Laboratory of Preparation and Applications of Environmental Friendly Materials of the Ministry of Education, Jilin Normal University, Changchun, 130103, China.

Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education, Jilin Normal University, Siping, 136000, China.

出版信息

Sci Rep. 2017 Oct 25;7(1):13972. doi: 10.1038/s41598-017-14598-0.

DOI:10.1038/s41598-017-14598-0
PMID:29070898
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5656616/
Abstract

We herein report the construction of four the novel fluorine-enriched conjugated microporous polymers (FCMP-600@1-4), which have permanent porous structures and plenty of fluorine atoms in the skeletons as effective sorption sites. Among them, FCMP-600@4 shows considerable adsorption capacity of CO of 5.35 mmol g at 273 K, and 4.18 mmol g at 298 K, which is higher than the reported values for most porous polymers. In addition, FCMP-600@1-4 display high selectivity of CO/N and high CH uptakes.

摘要

我们在此报告了四种新型富氟共轭微孔聚合物（FCMP - 600@1 - 4）的构建，它们具有永久多孔结构，且骨架中有大量氟原子作为有效的吸附位点。其中，FCMP - 600@4在273 K时对CO的吸附容量为5.35 mmol g，在298 K时为4.18 mmol g，高于大多数多孔聚合物的报道值。此外，FCMP - 600@1 - 4对CO/N表现出高选择性和对CH的高吸附量。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b6e/5656616/680c969e76aa/41598_2017_14598_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b6e/5656616/162ab0983ebc/41598_2017_14598_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b6e/5656616/f15767fe3d77/41598_2017_14598_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b6e/5656616/b380db2f237d/41598_2017_14598_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b6e/5656616/680c969e76aa/41598_2017_14598_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b6e/5656616/162ab0983ebc/41598_2017_14598_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b6e/5656616/f15767fe3d77/41598_2017_14598_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b6e/5656616/b380db2f237d/41598_2017_14598_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9b6e/5656616/680c969e76aa/41598_2017_14598_Fig4_HTML.jpg

相似文献

1
Synthesis of tunable porosity of fluorine-enriched porous organic polymer materials with excellent CO, CH and iodine adsorption.具有优异一氧化碳、甲烷及碘吸附性能的富氟多孔有机聚合物材料的可调孔隙率合成
Sci Rep. 2017 Oct 25;7(1):13972. doi: 10.1038/s41598-017-14598-0.
2
Synthesis and gas adsorption properties of tetra-armed microporous organic polymer networks based on triphenylamine.基于三苯胺的四臂微孔有机聚合物网络的合成及其气体吸附性能。
Macromol Rapid Commun. 2014 Apr;35(8):834-9. doi: 10.1002/marc.201300864. Epub 2014 Feb 6.
3
BILP-19-An Ultramicroporous Organic Network with Exceptional Carbon Dioxide Uptake.BILP-19-一种具有优异二氧化碳吸附性能的超微孔有机网络。
Molecules. 2017 Aug 12;22(8):1343. doi: 10.3390/molecules22081343.
4
Triptycene-based microporous polymer with pending tetrazole moieties for CO2 -capture application.基于三并苯的微孔聚合物，带有悬垂的四唑基团，用于 CO2 捕获应用。
Macromol Rapid Commun. 2013 Dec;34(23-24):1833-7. doi: 10.1002/marc.201300741. Epub 2013 Nov 11.
5
Template-free synthesis of porous carbon from triazine based polymers and their use in iodine adsorption and CO capture.无模板法合成基于三嗪的聚合物多孔碳及其在碘吸附和 CO 捕获中的应用。
Sci Rep. 2018 Jan 30;8(1):1867. doi: 10.1038/s41598-018-20003-1.
6
Remarkable CO2/CH4 selectivity and CO2 adsorption capacity exhibited by polyamine-decorated metal-organic framework adsorbents.聚胺修饰的金属有机框架吸附剂表现出显著的 CO2/CH4 选择性和 CO2 吸附容量。
Chem Commun (Camb). 2013 Aug 7;49(61):6873-5. doi: 10.1039/c3cc43352h. Epub 2013 Jun 24.
7
Unusually large microporous HKUST-1 via polyethylene glycol-templated synthesis: enhanced CO uptake with high selectivity over CH and N.通过聚乙二醇模板合成具有大微孔的 HKUST-1：对 CO 的高选择性吸收增强，对 CH 和 N 的选择性高。
Environ Sci Pollut Res Int. 2024 May;31(21):31355-31372. doi: 10.1007/s11356-024-33263-4. Epub 2024 Apr 17.
8
Hydroquinone and Quinone-Grafted Porous Carbons for Highly Selective CO2 Capture from Flue Gases and Natural Gas Upgrading.水合醌和醌接枝多孔碳在烟道气和天然气升级中对 CO2 的高选择性捕集。
Environ Sci Technol. 2015 Aug 4;49(15):9364-73. doi: 10.1021/acs.est.5b01652. Epub 2015 Jul 14.
9
Synthesis and characterization of functional thienyl-phosphine microporous polymers for carbon dioxide capture.噻吩基-膦微孔聚合物的合成与表征及其在二氧化碳捕集方面的应用。
Macromol Rapid Commun. 2013 Jul 25;34(14):1181-5. doi: 10.1002/marc.201300328. Epub 2013 Jun 12.
10
A Selenophene-Incorporated Metal-Organic Framework for Enhanced CO Uptake and Adsorption Selectivity.硒吩基金属有机框架用于增强 CO 吸收和吸附选择性。
Molecules. 2020 Sep 24;25(19):4396. doi: 10.3390/molecules25194396.

引用本文的文献

1
Active Polymers Decorated with Major Acid Groups for Water Treatment: Potentials and Challenges.用于水处理的含主要酸性基团的活性聚合物：潜力与挑战
Polymers (Basel). 2024 Dec 26;17(1):29. doi: 10.3390/polym17010029.
2
Nanoporous Metatitanic acid on γ-AlO aerogel for higher CO adsorption capacity and lower energy consumption.γ-氧化铝气凝胶负载的纳米多孔偏钛酸用于提高CO吸附容量及降低能耗
Sci Rep. 2024 Oct 2;14(1):22905. doi: 10.1038/s41598-024-74203-z.
3
A multifunctional microporous metal-organic framework: efficient adsorption of iodine and column-chromatographic dye separation.

本文引用的文献

1
A simple self-assembly strategy for ultrahigh surface area nitrogen-doped porous carbon nanospheres with enhanced adsorption and energy storage performances.一种用于制备具有超高比表面积、增强吸附和储能性能的氮掺杂多孔碳纳米球的简单自组装策略。
Chem Commun (Camb). 2017 Jun 20;53(50):6764-6767. doi: 10.1039/c7cc03212a.
2
Trends and challenges for microporous polymers.微孔聚合物的发展趋势与挑战。
Chem Soc Rev. 2017 Jun 6;46(11):3302-3321. doi: 10.1039/c7cs00071e.
3
Hypercrosslinked porous polymer materials: design, synthesis, and applications.
一种多功能微孔金属有机框架：碘的高效吸附及柱色谱染料分离
RSC Adv. 2018 Oct 26;8(63):36400-36406. doi: 10.1039/c8ra04648d. eCollection 2018 Oct 22.
4
Preparation of a reusable and pore size controllable porous polymer monolith and its catalysis of biodiesel synthesis.一种可重复使用且孔径可控的多孔聚合物整体材料的制备及其对生物柴油合成的催化作用。
RSC Adv. 2022 Apr 25;12(20):12363-12370. doi: 10.1039/d2ra01610a. eCollection 2022 Apr 22.
5
Fluorinated Iron(ii) clathrochelate units in metalorganic based copolymers: improved porosity, iodine uptake, and dye adsorption properties.金属有机基共聚物中的氟化铁（II）笼形螯合物单元：改善的孔隙率、碘吸收和染料吸附性能。
RSC Adv. 2021 Apr 21;11(25):14986-14995. doi: 10.1039/d1ra02357h.
6
Counter-Intuitive Magneto-Water-Wetting Effect to CO Adsorption at Room Temperature Using MgO/Mg(OH) Nanocomposites.室温下使用MgO/Mg(OH)纳米复合材料对CO吸附的反直觉磁水润湿效应
Materials (Basel). 2022 Jan 27;15(3):983. doi: 10.3390/ma15030983.
超交联多孔聚合物材料：设计、合成与应用。
Chem Soc Rev. 2017 Jun 6;46(11):3322-3356. doi: 10.1039/c6cs00851h.
4
Covalent organic frameworks based on Schiff-base chemistry: synthesis, properties and potential applications.基于席夫碱化学的共价有机框架：合成、性质及潜在应用。
Chem Soc Rev. 2016 Oct 10;45(20):5635-5671. doi: 10.1039/c5cs00878f.
5
Rational design and synthesis of a porous, task-specific polycarbazole for efficient CO2 capture.用于高效二氧化碳捕集的多孔、特定功能聚咔唑的合理设计与合成
Chem Commun (Camb). 2016 Mar 25;52(24):4454-7. doi: 10.1039/c6cc00573j.
6
Advances in theory and their application within the field of zeolite chemistry.沸石化学领域理论的进展及其应用。
Chem Soc Rev. 2015 Oct 21;44(20):7044-111. doi: 10.1039/c5cs00029g. Epub 2015 May 15.
7
Unprecedented high-temperature CO2 selectivity in N2-phobic nanoporous covalent organic polymers.在氮气憎性纳米多孔共价有机聚合物中表现出前所未有的高温 CO2 选择性。
Nat Commun. 2013;4:1357. doi: 10.1038/ncomms2359.
8
Element-organic frameworks with high permanent porosity.具有高永久孔隙率的元素有机框架。
Chem Commun (Camb). 2008 Jun 7(21):2462-4. doi: 10.1039/b718925g. Epub 2008 Mar 26.
9
Polymers of intrinsic microporosity (PIMs): organic materials for membrane separations, heterogeneous catalysis and hydrogen storage.固有微孔聚合物（PIMs）：用于膜分离、多相催化和储氢的有机材料。
Chem Soc Rev. 2006 Aug;35(8):675-83. doi: 10.1039/b600349d. Epub 2006 Mar 17.