Tansell Alexander J, Jones Corey L, Easun Timothy L
School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, CF10 3AT, UK.
Chem Cent J. 2017 Oct 11;11(1):100. doi: 10.1186/s13065-017-0330-0.
Over the past few decades, metal-organic frameworks (MOFs) have proved themselves as strong contenders in the world of porous materials, standing alongside established classes of compounds such as zeolites and activated carbons. Following extensive investigation into the porosity of these materials and their gas uptake properties, the MOF community are now branching away from these heavily researched areas, and venturing into unexplored avenues. Ranging from novel synthetic routes to post-synthetic functionalisation of frameworks, host-guest properties to sensing abilities, this review takes a sidestep away from increasingly 'traditional' approaches in the field, and details some of the more curious qualities of this relatively young family of materials.
在过去几十年里，金属有机框架材料（MOFs）已证明自身是多孔材料领域的有力竞争者，与沸石和活性炭等成熟的化合物类别并驾齐驱。在对这些材料的孔隙率及其气体吸附特性进行广泛研究之后，MOF研究群体现在正从这些研究深入的领域转向，探索未开发的途径。从新颖的合成路线到框架的后合成功能化，从主客体性质到传感能力，本综述避开了该领域日益“传统”的方法，详细介绍了这个相对年轻的材料家族的一些更为奇特的特性。
