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低温台式合成全无机钙钛矿纳米线。

Low-temperature benchtop-synthesis of all-inorganic perovskite nanowires.

机构信息

Institute of Electronic Structure and Laser, Foundation for Research and Technology - Hellas, Vassilika Vouton, Heraklion, 71110, Crete, Greece.

出版信息

Nanoscale. 2017 Nov 30;9(46):18202-18207. doi: 10.1039/c7nr06404g.

Abstract

A facile, low-temperature precipitation-based method is utilized for the synthesis of ultra-thin and highly uniform cesium lead bromide perovskite nanowires (NWs). The reactions facilitate the NWs' crystalline nature over micron-size lengths, while they impart tailored nanowire widths that range from the quantum confinement regime (∼7 nm) down to 2.6 nm. This colloidal synthesis approach is the first of its kind that is carried out on the work-bench, without demanding chemical synthesis equipment. Importantly, the NWs' photoluminescence is shown to improve over time, with no requirement for tedious post-synthesis surface treatment.

摘要

一种简单、低温的沉淀法被用于合成超薄且高度均匀的卤化铯铅钙钛矿纳米线(NWs)。该反应促进了 NWs 在微米长度上的晶态特性,同时赋予了从量子限制(约 7nm)到 2.6nm 的定制纳米线宽度。这种胶体合成方法是同类中首次在工作台上进行的,而不要求使用化学合成设备。重要的是,NWs 的光致发光性能随着时间的推移而提高,不需要繁琐的后合成表面处理。

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