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六方型与锚定 MWCNTs:设计挠性固态对称超级电容器装置的初探。

Hexagonal VS Anchored MWCNTs: First Approach to Design Flexible Solid-State Symmetric Supercapacitor Device.

机构信息

Nano Materials and Device Laboratory, Department of Physics, Visvesvaraya National Institute of Technology , South Ambazari Road, Nagpur 440010, Maharashtra, India.

出版信息

ACS Appl Mater Interfaces. 2017 Dec 27;9(51):44880-44891. doi: 10.1021/acsami.7b13908. Epub 2017 Dec 15.

Abstract

Transition metal chalcogenides (TMCs) embedded with a carbon network are gaining much attention because of their high power capability, which can be easily integrated to portable electronic devices. Facile chemical route has been explored to synthesize hexagonal structured VS nanoparticles onto multiwalled carbon nanotubes (MWCNTs) matrix. Such surface-modified VS/MWCNTs electrode has boosted the electrochemical performance to reach high capacitance to 830 F/g and excellent stability to 95.9% over 10 000 cycles. Designed flexible solid-state symmetric supercapacitor device (FSSD) with a wide voltage window of 1.6 V exhibited maximum gain in specific capacitance value of 182 F/g at scan rate of 2 mV/s along with specific energy of 42 Wh/kg and a superb stability of 93.2% over 5000 cycles. As a practical approach, FSSD has lightened up "VNIT" panel consisting of 21 red LEDs.

摘要

过渡金属硫属化物(TMCs)嵌入碳网络中,由于其高功率能力而备受关注,这使其可以轻松集成到便携式电子设备中。已经探索了简单的化学路线,以将六方结构的 VS 纳米颗粒合成到多壁碳纳米管(MWCNTs)基体上。这种经过表面修饰的 VS/MWCNTs 电极提高了电化学性能,达到了 830 F/g 的高电容和 10000 次循环后 95.9%的优异稳定性。设计的具有 1.6 V 宽电压窗口的柔性固态对称超级电容器装置(FSSD)在 2 mV/s 的扫描速率下,比电容值最大增加了 182 F/g,同时具有 42 Wh/kg 的比能量和 5000 次循环后 93.2%的出色稳定性。作为一种实用方法,FSSD 点亮了由 21 个红色 LED 组成的“VNIT”面板。

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