College of Chemistry and Material Sciences, Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi'an, 710069, P. R. China.
Chemistry. 2018 May 2;24(25):6506-6518. doi: 10.1002/chem.201705415. Epub 2018 Feb 5.
Metal-organic frameworks (MOFs), as an important kind of porous inorganic-organic hybrid materials with inherent outstanding physicochemistry characteristics, can be widely applied as versatile precursors for the facile preparation of functional MOF-derived materials. However, there are plenty of sophisticated factors during the synthetic process, which is far from reaching the goal of effectively controlling the nature of MOF-derived materials (such as the composition, morphology and surface area). Therefore, it is urgently necessary to develop regular protocols and concepts for controllable syntheses of MOF-derived materials. In this minireview, we mainly summarize and analyze complicated factors in the fabrication of MOF-derived materials according to recently reported literatures, and this provides a new insight into the rational design and syntheses of MOF-derived materials.
金属-有机框架(MOFs)作为一类具有固有突出物理化学特性的多孔无机-有机杂化材料,可以广泛用作多功能 MOF 衍生材料的简便制备的通用前体。然而,在合成过程中存在许多复杂的因素,远远没有达到有效控制 MOF 衍生材料性质(如组成、形态和表面积)的目标。因此,迫切需要开发用于 MOF 衍生材料可控合成的常规方案和概念。在这篇综述中,我们主要根据最近报道的文献总结和分析了 MOF 衍生材料制备中的复杂因素,这为 MOF 衍生材料的合理设计和合成提供了新的见解。