Shi Zhengqi, Jayatissa Ahalapitiya H
Nanotechnology and MEMS Laboratory, Department of Mechanical, Industrial, and Manufacturing Engineering (MIME), University of Toledo, Toledo, OH 43606, USA.
Materials (Basel). 2017 Dec 27;11(1):36. doi: 10.3390/ma11010036.
Commercial solar cells have a power conversion efficiency (PCE) in the range of 10-22% with different light absorbers. Graphene, with demonstrated unique structural, physical, and electrical properties, is expected to bring the positive effects on the development of thin film solar cells. Investigations have been carried out to understand whether graphene can be used as a front and back contacts and active interfacial layer in solar cell fabrication. In this review, the current progress of this research is analyzed, starting from the graphene and graphene-based Schottky diode. Also, the discussion was focused on the progress of graphene-incorporated thin film solar cells that were fabricated with different light absorbers, in particular, the synthesis, fabrication, and characterization of devices. The effect of doping and layer thickness of graphene on PCE was also included. Currently, the PCE of graphene-incorporated bulk-heterojunction devices have enhanced in the range of 0.5-3%. However, device durability and cost-effectiveness are also the challenging factors for commercial production of graphene-incorporated solar cells. In addition to the application of graphene, graphene oxides have been also used in perovskite solar cells. The current needs and likely future investigations for graphene-incorporated solar cells are also discussed.
商业太阳能电池使用不同的光吸收剂时,功率转换效率(PCE)在10%至22%之间。石墨烯具有独特的结构、物理和电学性质,有望对薄膜太阳能电池的发展产生积极影响。人们已经开展了相关研究,以了解石墨烯是否可用于太阳能电池制造中的正面和背面接触以及活性界面层。在这篇综述中,从石墨烯和基于石墨烯的肖特基二极管入手,分析了该研究的当前进展。此外,讨论聚焦于采用不同光吸收剂制造的含石墨烯薄膜太阳能电池的进展,特别是器件的合成、制造和表征。还包括了石墨烯的掺杂和层厚对PCE的影响。目前,含石墨烯体相异质结器件的PCE提高了0.5%至3%。然而,器件耐久性和成本效益也是含石墨烯太阳能电池商业化生产面临的挑战因素。除了石墨烯的应用,氧化石墨烯也已用于钙钛矿太阳能电池。文中还讨论了含石墨烯太阳能电池当前的需求以及未来可能的研究方向