Tejo Ciputra, Pang Jia Hao, Ong Derek Yiren, Oi Miku, Uchiyama Masanobu, Takita Ryo, Chiba Shunsuke
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore.
Chem Commun (Camb). 2018 Feb 13;54(14):1782-1785. doi: 10.1039/c8cc00289d.
A new protocol for the dearylation of arylphosphine oxides was developed using sodium hydride (NaH) in the presence of lithium iodide (LiI). The transient sodium phosphinite could be functionalized with a range of electrophiles in a one-pot fashion.
开发了一种在碘化锂（LiI）存在下使用氢化钠（NaH）进行芳基氧化膦脱芳基化的新方案。瞬态次膦酸钠可以通过一锅法用一系列亲电试剂进行官能化。
