镍催化的芳基和苄基 2-吡啶基醚的碳-氧键还原反应。
Nickel-catalyzed C-O bond reduction of aryl and benzyl 2-pyridyl ethers.
作者信息
Li Jing, Wang Zhong-Xia
机构信息
CAS Key Laboratory of Soft Matter Chemistry, Hefei National Laboratory for Physical Sciences at Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China.
出版信息
Chem Commun (Camb). 2018 Feb 22;54(17):2138-2141. doi: 10.1039/c7cc09668b.
The reduction of aryl and benzyl 2-pyridyl ethers with sodium isopropoxide was carried out via nickel-catalyzed C-OPy bond cleavage, giving reductive products in reasonable to excellent yields. This method allowed the 2-pyridyloxy group to be directly removed with high efficiency, mild reaction conditions, and good compatibility of functional groups.
通过镍催化的C-OPy键裂解，用异丙醇钠还原芳基和苄基2-吡啶基醚，以合理至优异的产率得到还原产物。该方法能够在高效、温和的反应条件以及良好的官能团兼容性下直接去除2-吡啶氧基。
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