Henkel Ireland Operations & Research Limited, Whitestown, Dublin 24, Ireland.
School of Chemistry, National University of Ireland Galway, University Road, Galway H91 TK33, Ireland.
Molecules. 2018 Feb 20;23(2):465. doi: 10.3390/molecules23020465.
Cyanoacrylates (CAs) are well-known fast-setting adhesives, which are sold as liquids in the presence of stabilizers. Rapid anionic polymerization on exposure to surface moisture is responsible for instant adhesion. The more difficult, but synthetically more useful radical polymerization is only possible under acidic conditions. Recommendations on the handling of CAs and the resulting polymers are provided herein. In this review article, after a general description of monomer and polymer properties, radical homo- and copolymerization studies are described, along with an overview of nanoparticle preparations. A summary of our recently reported radical polymerization of CAs, using reversible addition-fragmentation chain transfer (RAFT) polymerization, is provided.
氰基丙烯酸酯（CAs）是众所周知的速凝胶粘剂，在稳定剂存在的情况下以液体形式出售。暴露于表面水分时，快速阴离子聚合负责即时粘附。更困难但合成上更有用的自由基聚合只有在酸性条件下才有可能。本文提供了有关 CAs 及其聚合物的处理建议。在这篇综述文章中，在对单体和聚合物性质进行了一般性描述之后，描述了自由基均聚和共聚研究，并概述了纳米颗粒的制备。提供了我们最近使用可逆加成-断裂链转移（RAFT）聚合报告的 CAs 自由基聚合的总结。
