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使用瞬态导向基团实现苯甲醛与芳烃的直接脱氢芳基化反应。

Direct Dehydrogenative Arylation of Benzaldehydes with Arenes Using Transient Directing Groups.

机构信息

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Department of Chemistry & Materials Science , Northwest University , Xi'an 710069 , P. R. China.

出版信息

Org Lett. 2018 Apr 6;20(7):1794-1797. doi: 10.1021/acs.orglett.8b00292. Epub 2018 Mar 9.

DOI:10.1021/acs.orglett.8b00292
PMID:29522346
Abstract

The utilization of the transient directing strategy into the direct oxidative dehydrogenative arylation of aldehydes with arenes was reported for the first time. Featured by mild reaction conditions, good functional group compatibility, and great regioselectivity, the method should find broad applications in new medicine and material development and discovery processes.

摘要

首次报道了瞬态导向策略在醛与芳基的直接氧化脱氢芳基化反应中的应用。该方法具有反应条件温和、官能团兼容性好、区域选择性高的特点,应在新药和新材料的开发和发现过程中有广泛的应用。

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