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与表面无关的高可拉伸且可弯曲的导电MXene多层膜。

Surface-agnostic highly stretchable and bendable conductive MXene multilayers.

作者信息

An Hyosung, Habib Touseef, Shah Smit, Gao Huili, Radovic Miladin, Green Micah J, Lutkenhaus Jodie L

机构信息

Artie McFerrin Department of Chemical Engineering, Texas A&M University, College Station, TX 77843, USA.

Department of Mechanical Engineering, Texas A&M University, College Station, TX 77843, USA.

出版信息

Sci Adv. 2018 Mar 9;4(3):eaaq0118. doi: 10.1126/sciadv.aaq0118. eCollection 2018 Mar.

Abstract

Stretchable, bendable, and foldable conductive coatings are crucial for wearable electronics and biometric sensors. These coatings should maintain functionality while simultaneously interfacing with different types of surfaces undergoing mechanical deformation. MXene sheets as conductive two-dimensional nanomaterials are promising for this purpose, but it is still extremely difficult to form surface-agnostic MXene coatings that can withstand extreme mechanical deformation. We report on conductive and conformal MXene multilayer coatings that can undergo large-scale mechanical deformation while maintaining a conductivity as high as 2000 S/m. MXene multilayers are successfully deposited onto flexible polymer sheets, stretchable poly(dimethylsiloxane), nylon fiber, glass, and silicon. The coating shows a recoverable resistance response to bending (up to 2.5-mm bending radius) and stretching (up to 40% tensile strain), which was leveraged for detecting human motion and topographical scanning. We anticipate that this discovery will allow for the implementation of MXene-based coatings onto mechanically deformable objects.

摘要

可拉伸、可弯曲和可折叠的导电涂层对于可穿戴电子产品和生物识别传感器至关重要。这些涂层应在与经历机械变形的不同类型表面接触的同时保持功能。作为导电二维纳米材料的MXene片材有望用于此目的,但形成能够承受极端机械变形的与表面无关的MXene涂层仍然极其困难。我们报道了一种导电且保形的MXene多层涂层,该涂层能够承受大规模机械变形,同时保持高达2000 S/m的电导率。MXene多层膜成功沉积在柔性聚合物片材、可拉伸的聚二甲基硅氧烷、尼龙纤维、玻璃和硅上。该涂层对弯曲(弯曲半径可达2.5毫米)和拉伸(拉伸应变可达40%)表现出可恢复的电阻响应,可用于检测人体运动和地形扫描。我们预计这一发现将使基于MXene的涂层能够应用于机械可变形物体上。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9e3d/5844711/0bf245d22ccf/aaq0118-F1.jpg

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