Lee Tai-Kuang, Liuand Chao-Te, Lee Wen-Hsi
J Nanosci Nanotechnol. 2017 Jan;17(1):363-9. doi: 10.1166/jnn.2017.10615.
Recently, Thin Film Transistors (TFTs) have been studied widely because of potential applications in low cost, low-temperature process and flexible displays. They can be fabricated by easy processes based on solution methods. But the mobility of organic TFTs is lower and the threshold voltage is higher than amorphous Si TFTs. In order to enhance the channel mobility and satisfy with the requirement of low-cost fabrication, we prepare a low-cost, mask-free, reduced material wastage, deposited technology using transparent, directly printable, air-stable semiconductor slurries and dielectric solutions. In our investigations, we attempt to obtain a high performance and low-cost TFT via preparing materials, designing device structure, and using PZT inkjet-printing technology. A stable and non-precipitated metal oxide ink with appropriate doping was prepared for the fabrication of an InxZn1.5Sn1.0 (IZTO) by PZT inkjet-printing. The soluble direct-printing process is a powerful tool for material research and implies that the printable materials and the printing technology enable the use of all-printed low-cost flexible displays and other transparent electronic applications. Transparent materials including dielectric PVP, conductive carbon nanotube (CNT) and active IZTO were employed into the fabrication of our PZT inkjet-printing process. After annealed at 180 °C, The experimental all-printed TFT exhibit the carrier mobility of 0.194 cm2/Vs, sub-threshold slope of 20 V/decade, and the threshold voltage of 5 V, initially. All-inkjet-printed films have great transparency, potentially in transparent electronics and the transmittance pattern in visible part of the spectrum (400–700 nm) is over 80%.
近年来,薄膜晶体管(TFT)因其在低成本、低温工艺和柔性显示器方面的潜在应用而受到广泛研究。它们可以通过基于溶液法的简便工艺制造。但有机TFT的迁移率低于非晶硅TFT,且阈值电压更高。为了提高沟道迁移率并满足低成本制造的要求,我们采用透明、可直接印刷、空气稳定的半导体浆料和介电溶液,制备了一种低成本、无掩膜、材料浪费少的沉积技术。在我们的研究中,我们试图通过制备材料、设计器件结构以及使用PZT喷墨印刷技术来获得高性能、低成本的TFT。制备了一种具有适当掺杂的稳定且不沉淀的金属氧化物墨水,用于通过PZT喷墨印刷制造InxZn1.5Sn1.0(IZTO)。可溶性直接印刷工艺是材料研究的有力工具,这意味着可印刷材料和印刷技术能够实现全印刷低成本柔性显示器及其他透明电子应用。包括介电PVP、导电碳纳米管(CNT)和活性IZTO在内的透明材料被用于我们的PZT喷墨印刷工艺的制造中。在180℃退火后,实验性的全印刷TFT最初表现出0.194 cm2/Vs的载流子迁移率、20 V/十倍频程的亚阈值斜率以及5 V的阈值电压。全喷墨印刷薄膜具有很高的透明度,在透明电子领域具有潜在应用,并且在光谱可见光部分(400 - 700 nm)的透过率图案超过80%。