Chen Qiaomei, Pei Zhiqiang, Xu Yanshuang, Li Zhen, Yang Yang, Wei Yen, Ji Yan
MOE Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology , Department of Chemistry , Tsinghua University , Beijing 100084 , China . Email:
Simpson Querrey Institute for BioNanotechnology , Northwestern University , Chicago , Illinois 60611 , USA.
Chem Sci. 2017 Nov 1;9(3):623-628. doi: 10.1039/c7sc02967e. eCollection 2018 Jan 21.
Efficient and cost-effective solar steam generation requires self-floating evaporators which can convert light into heat, prevent unnecessary heat loss and greatly accelerate evaporation without solar concentrators. Currently, the most efficient evaporators (efficiency of ∼80% under 1 sun) are invariably built from inorganic materials, which are difficult to mold into monolithic sheets. Here, we present a new polymer which can be easily solution processed into a self-floating monolithic foam. The single-component foam can be used as an evaporator with an efficiency at 1 sun comparable to that of the best graphene-based evaporators. Even at 0.5 sun, the efficiency can reach 80%. Moreover, the foam is mechanically strong, thermally stable to 300 °C and chemically resistant to organic solvents.
高效且经济高效的太阳能蒸汽产生需要自漂浮蒸发器,这种蒸发器能够将光转化为热,防止不必要的热损失,并在没有太阳能聚光器的情况下极大地加速蒸发。目前,最有效的蒸发器(在1个太阳光照强度下效率约为80%)无一例外都是由无机材料制成的,而无机材料很难模压成整体薄片。在此,我们展示了一种新型聚合物,它可以很容易地通过溶液加工制成自漂浮的整体泡沫。这种单组分泡沫可用作蒸发器,在1个太阳光照强度下的效率与最好的基于石墨烯的蒸发器相当。即使在0.5个太阳光照强度下,效率也能达到80%。此外,这种泡沫机械强度高,热稳定性可达300℃,并且对有机溶剂具有化学抗性。