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导电聚合物在能源、环境修复及化学-手性传感器领域的应用

Conducting Polymers in the Fields of Energy, Environmental Remediation, and Chemical-Chiral Sensors.

作者信息

Ibanez Jorge G, Rincón Marina E, Gutierrez-Granados Silvia, Chahma M'hamed, Jaramillo-Quintero Oscar A, Frontana-Uribe Bernardo A

机构信息

Departamento de Ingeniería y Ciencias Químicas , Universidad Iberoamericana , Prolongación Paseo de la Reforma 880 , 01219 Ciudad de México , Mexico.

Instituto de Energías Renovables , Universidad Nacional Autónoma de México , Apartado Postal 34 , 62580 , Temixco , MOR , Mexico.

出版信息

Chem Rev. 2018 May 9;118(9):4731-4816. doi: 10.1021/acs.chemrev.7b00482. Epub 2018 Apr 9.

DOI:10.1021/acs.chemrev.7b00482
PMID:29630346
Abstract

Conducting polymers (CPs), thanks to their unique properties, structures made on-demand, new composite mixtures, and possibility of deposit on a surface by chemical, physical, or electrochemical methodologies, have shown in the last years a renaissance and have been widely used in important fields of chemistry and materials science. Due to the extent of the literature on CPs, this review, after a concise introduction about the interrelationship between electrochemistry and conducting polymers, is focused exclusively on the following applications: energy (energy storage devices and solar cells), use in environmental remediation (anion and cation trapping, electrocatalytic reduction/oxidation of pollutants on CP based electrodes, and adsorption of pollutants) and finally electroanalysis as chemical sensors in solution, gas phase, and chiral molecules. This review is expected to be comprehensive, authoritative, and useful to the chemical community interested in CPs and their applications.

摘要

导电聚合物(CPs)由于其独特的性质、按需制造的结构、新型复合混合物以及通过化学、物理或电化学方法在表面沉积的可能性,在过去几年中迎来了复兴,并已广泛应用于化学和材料科学的重要领域。由于关于导电聚合物的文献数量众多,本综述在简要介绍了电化学与导电聚合物之间的相互关系之后,将专门聚焦于以下应用:能源(储能装置和太阳能电池)、环境修复中的应用(阴离子和阳离子捕获、基于导电聚合物的电极上污染物的电催化还原/氧化以及污染物的吸附),最后是作为溶液、气相和手性分子中的化学传感器的电分析。预计本综述对关注导电聚合物及其应用的化学界来说将是全面、权威且有用的。

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