Nascimento Denis W S, de Moura Márcia R, Mattoso Luiz H C, Aouada Fauze A
J Nanosci Nanotechnol. 2017 Jan;17(1):821-27. doi: 10.1166/jnn.2017.12664.
In this paper, series of novel nanocomposite hydrogels based on polyacrylamide (PAAm), carboxymethylcellulose (CMC) and nanoclay were synthesized. Hydrophilic, kinetic, spectroscopic and morphological properties were investigated as function of their constituents. Spectroscopic properties confirmed the obtaining of the nanocomposites. It was also observed that the nanocomposites have walls of pores with a more rugged morphology compared with the morphology of the hydrogel without clay, contributing to repel the water molecules. Besides, the results showed that the velocity and quantity of water uptake may be controlled by adjusting of matrix rigidity, i.e., nanoclay content into polymeric matrix. This behavior is required to future application in agriculture fields, specifically as carrier vehicle in controlled release of agrochemicals. Thus, these nanocomposites have technological application.
本文合成了一系列基于聚丙烯酰胺(PAAm)、羧甲基纤维素(CMC)和纳米黏土的新型纳米复合水凝胶。研究了其亲水性、动力学、光谱和形态学性质与其成分的关系。光谱性质证实了纳米复合材料的形成。还观察到,与不含黏土的水凝胶形态相比,纳米复合材料具有形态更粗糙的孔壁,有助于排斥水分子。此外,结果表明,吸水速度和吸水量可以通过调节基质刚性,即聚合物基质中的纳米黏土含量来控制。这种行为对于未来在农业领域的应用,特别是作为农用化学品控释的载体来说是必需的。因此,这些纳米复合材料具有技术应用价值。