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天然糖:高效剥离无机层状纳米材料的绿色助剂。

Natural Sugar: A Green Assistance To Efficiently Exfoliate Inorganic Layered Nanomaterials.

机构信息

Qinghai Key Laboratory of Qinghai-Tibet Plateau Biological Resources , Northwest Institute of Plateau Biology, Chinese Academy of Sciences , Xining , 810008 Qinghai , P. R. China.

出版信息

Inorg Chem. 2018 May 7;57(9):5560-5566. doi: 10.1021/acs.inorgchem.8b00525. Epub 2018 Apr 10.

Abstract

We have demonstrated that natural sugars can efficiently exfoliate inorganic layered nanomaterials with direct stirring. The representative transition-metal dichalcogenides (MoS and WS), transition-metal oxide (MoO), and graphene were explored, and the formation of ultrathin nanosheets was verified. Glucose and MoS selected each other as the perfect partner with superior exfoliation and excellent properties. The obtained inorganic layered nanosheets possess favorable stability and dispersity, which renders it suitable for direct homogeneous liquid applications, such as catalytic activities and sensors. With a high-throughput and green process, the sugar-assisted method may offer new ideas for inorganic layered nanomaterials synthesis and applications in a more ecofriendly way.

摘要

我们已经证明,天然糖可以通过直接搅拌有效地剥离无机层状纳米材料。我们探索了具有代表性的过渡金属二卤化物(MoS 和 WS)、过渡金属氧化物(MoO)和石墨烯,验证了它们形成超薄纳米片的过程。葡萄糖和 MoS 彼此选择作为完美的搭档,具有优异的剥离效果和性能。所得的无机层状纳米片具有良好的稳定性和分散性,非常适合直接进行均质液体应用,如催化活性和传感器。这种糖辅助方法具有高通量和绿色工艺的特点,为无机层状纳米材料的合成和应用提供了新的思路,使其更加环保。

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