Zhao Shu-Na, Wang Guangbo, Poelman Dirk, Voort Pascal Van Der
Department of Chemistry, Center for Ordered Materials, Organometallics and Catalysis (COMOC), Ghent University, Krijgslaan 281 (S3), 9000 Gent, Belgium.
LumiLab, Department of Solid State Sciences, Ghent University, Krijgslaan 281 (S1), 9000 Gent, Belgium.
Materials (Basel). 2018 Apr 7;11(4):572. doi: 10.3390/ma11040572.
In recent years, lanthanide metal-organic frameworks (LnMOFs) have developed to be an interesting subclass of MOFs. The combination of the characteristic luminescent properties of Ln ions with the intriguing topological structures of MOFs opens up promising possibilities for the design of LnMOF-based chemical sensors. In this review, we present the most recent developments of LnMOFs as chemical sensors by briefly introducing the general luminescence features of LnMOFs, followed by a comprehensive investigation of the applications of LnMOF sensors for cations, anions, small molecules, nitroaromatic explosives, gases, vapors, pH, and temperature, as well as biomolecules.
近年来,镧系金属有机框架(LnMOFs)已发展成为金属有机框架中一个有趣的子类。Ln离子的特征发光特性与金属有机框架引人入胜的拓扑结构相结合,为基于LnMOF的化学传感器设计开辟了广阔的前景。在本综述中,我们通过简要介绍LnMOFs的一般发光特性,展示了LnMOFs作为化学传感器的最新进展,随后全面研究了LnMOF传感器在阳离子、阴离子、小分子、硝基芳香族炸药、气体、蒸汽、pH值、温度以及生物分子方面的应用。