Copper-loaded nanocellulose sponge as a sustainable catalyst for regioselective hydroboration of alkynes.

It is desirable for catalyst supports to be biodegradable, easily-modifiable, and possessing high surface area. In this work, thiolated nanocellulose sponge was prepared from hydrolytic silane condensation of cellulose nanofibrils (CNF) and used as a green support to immobilize copper cations via in situ Cu to Cu reduction and complexation. The sponge featured high porosity (90.5%) and low density (29.4 mg/cm) with regular morphology. The sponge easily recovered 94% of its original shape in water after experiencing 80% deformation under stress of 95 kPa. When used in catalyzing hydroboration of alkynes, excellent conversion and up to 99% regioselectivity were achieved with the copper-loaded sponge. The sponge-supported catalysts worked well in the absence of additional ligands, had a broad substrate scope, and retained 93% of their activity after six catalytic cycles. This simple and scalable strategy offers an efficient route for immobilizing metal catalysts on porous supports.