State Key Laboratory of Luminescent Materials and Devices, Center for Aggregation-Induced Emission, South China University of Technology, Guangzhou, 510640, China.
Department of Chemistry, Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, The Hong Kong University of Science & Technology, Clear Water Bay, Kowloon, Hong Kong.
Macromol Rapid Commun. 2018 Jun;39(11):e1800098. doi: 10.1002/marc.201800098. Epub 2018 Apr 22.
Click polymerization, a powerful synthetic technique to construct polymers with unique structures and advanced functions, is of crucial importance in the areas of polymer and material sciences. A variety of click polymerizations such as azide-alkyne, thiol-yne, amino-yne, and hydroxyl-yne reactions have been established, wherein the catalytic systems play an indispensable role in realizing these highly practical reactions based on triple-bond building blocks, as they directly influence the efficiencies of the click polymerizations and the performances of the resultant polymers. The vital employment of catalysts is reviewed and their developments from innovative discoveries to the eminent position are outlined. Moreover, the challenges and perspectives in this area are also briefly discussed.
点击聚合，一种构建具有独特结构和先进功能的聚合物的强大合成技术，在聚合物和材料科学领域至关重要。已经建立了各种点击聚合反应，例如叠氮-炔、硫醇-炔、氨基-炔和羟基-炔反应，其中催化体系在实现基于三键构建块的这些高度实用的反应中起着不可或缺的作用，因为它们直接影响点击聚合的效率和所得聚合物的性能。综述了催化剂的重要应用，并概述了从创新发现到杰出地位的发展历程。此外，还简要讨论了该领域的挑战和展望。
