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分级超透明氧化锆(5Y-PSZ)兼具强度与多种功能。

Graded Ultra-Translucent Zirconia (5Y-PSZ) for Strength and Functionalities.

机构信息

1 Department of Biomaterials and Biomimetics, New York University College of Dentistry, New York, NY, USA.

2 Department of Stomatology, Guizhou Medical University, Guiyang, China.

出版信息

J Dent Res. 2018 Oct;97(11):1222-1228. doi: 10.1177/0022034518771287. Epub 2018 Apr 25.

Abstract

Ultra-translucent zirconias are drawing immense attention due to their fascinating esthetic appearance. However, the high translucency came at the expense of diminishing strength along with the reduced ability of transformation toughening due to the increased cubic zirconia content. We aim to address these issues by infiltrating glass on the surface of an ultra-translucent zirconia (5Y-PSZ). Glasses of different shades can be used and the resulting graded glass/zirconia layer is expected to improve the material's flexural strength without compromising its esthetics. We also aim to elucidate how clinically relevant surface treatments-namely, air abrasion, glazing, or polishing-affect the fracture resistance of these zirconias with a high cubic content. All surface treatments were performed on bar-shaped (2 × 3 × 25 mm) and plate-shaped (12 × 12 × 1 mm) specimens, which were then subjected to a 4-point bending test and translucency measurements, respectively. 5Y-PSZ proved to be significantly more translucent than 3Y-TZP but also much weaker. Our hypothesis was accepted, as the strength of the glass-infiltrated ultra-translucent 5Y-PSZ (582 ± 20 MPa) is over 70% higher than its uninfiltrated counterpart (324 ± 57 MPa). Its strength is also over 25% higher than the highly polished 5Y-PSZ (467 ± 38 MPa). In addition, the translucency of 5Y-PSZ (translucency parameter [ TP] = 34, contrast ratio [ CR] = 0.31) is not affected by glass infiltration ( TP = 34, CR = 0.32) when the residual surface glass is removed by gentle polishing using 6- and then 3-µm diamond grits. Finally, both air abrasion and the presence of a glaze layer on the tensile surface decreased flexural strength significantly, being 274 ± 55 and 211 ± 21 MPa, respectively. With a combined high strength and translucency, the newly developed glass-infiltrated 5Y-PSZ may be considered a suitable material for next-generation, damage-resistant, and esthetic dental restorations.

摘要

由于其迷人的美学外观,超透明氧化锆引起了极大的关注。然而,由于增加了立方氧化锆的含量,透光率的提高是以强度降低和相变增韧能力降低为代价的。我们的目标是通过在超透明氧化锆(5Y-PSZ)表面渗透玻璃来解决这些问题。可以使用不同色调的玻璃,并且预期所得的分级玻璃/氧化锆层将改善材料的弯曲强度,而不会影响其美学效果。我们还旨在阐明临床上相关的表面处理(即喷砂,上釉或抛光)如何影响高立方含量的这些氧化锆的抗断裂性。所有表面处理均在棒状(2×3×25mm)和板状(12×12×1mm)样品上进行,然后分别进行四点弯曲测试和透光率测量。5Y-PSZ 被证明比 3Y-TZP 明显更透明,但也更弱。我们的假设被接受了,因为玻璃渗透的超透明 5Y-PSZ(582±20MPa)的强度比未渗透的 5Y-PSZ(324±57MPa)高 70%以上。它的强度也比高度抛光的 5Y-PSZ(467±38MPa)高 25%以上。此外,当通过使用 6μm 和 3μm 金刚石磨料进行轻微抛光来去除残留的表面玻璃时,5Y-PSZ 的透光率(透光率参数[TP]=34,对比度比[CR]=0.31)不受玻璃渗透的影响(TP=34,CR=0.32)。最后,喷砂和拉伸表面上釉层的存在都会显著降低弯曲强度,分别为 274±55MPa 和 211±21MPa。具有高强度和高透光率的新型玻璃渗透 5Y-PSZ 可被认为是用于下一代抗损伤和美观的牙科修复体的合适材料。

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