铜催化 1,3-二烯与 3-溴吡啶的杂芳基硼化反应：协同取代。
Copper-Catalyzed Heteroarylboration of 1,3-Dienes with 3-Bromopyridines: A cine Substitution.
机构信息
Department of Chemistry, Indiana University, 800 E. Kirkwood Ave., Bloomington, IN, 47401, USA.
出版信息
Angew Chem Int Ed Engl. 2018 May 22;57(21):6146-6149. doi: 10.1002/anie.201801139. Epub 2018 Apr 26.
Abstract
A method for the heteroarylboration of 1,3-dienes is presented. The process involves an unusual cine substitution of 3-bromopyridine derivatives to deliver highly functionalized heterocyclic products. Mechanistic studies are included that clarify the details of this unusual process.
摘要
本文提出了一种用于 1,3-二烯杂芳基硼化的方法。该过程涉及 3-溴吡啶衍生物的不寻常的同面取代，以提供高官能化的杂环产物。包括的机理研究阐明了这个不寻常过程的细节。
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