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室内环境中的多氯联苯和有机氯农药——加拿大和捷克共和国室内污染的比较。

PCBs and organochlorine pesticides in indoor environments - A comparison of indoor contamination in Canada and Czech Republic.

机构信息

RECETOX, Masaryk University, Kamenice 753/5, Pavilion A29, 62500, Brno, Czech Republic.

RECETOX, Masaryk University, Kamenice 753/5, Pavilion A29, 62500, Brno, Czech Republic.

出版信息

Chemosphere. 2018 Sep;206:622-631. doi: 10.1016/j.chemosphere.2018.05.016. Epub 2018 May 3.

Abstract

Polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs) are restricted compounds that are ubiquitously detected in the environment, including indoor matrices such as air and residential dust. We report concentrations of PCBs and selected OCPs in indoor air and dust from homes in Canada (23 homes) and Czech Republic (20 homes). Indoor air concentrations of PCBs and OCPs were ∼10 times higher than that outdoors. PCB concentrations of ∼450 ng/m were similar in both countries, higher in homes built before the restrictions on PCBs, and had congener profiles consistent with PCB mixtures manufactured or used in each country. All OCP air concentrations were higher in the Czech Republic than in the Canadian samples, suggesting greater indoor use of, for example, DDT and HCH. These data emphasize the persistence of these organochlorine compounds indoors and their presence in homes even decades after new usage was prohibited. Indoor levels of these legacy POPs remain at similar concentrations to compounds of current concern, such as brominated flame retardants and perfluorinated alkyl substances, emphasizing that they deserve ongoing attention in view of knowledge of PCB and OCP toxicity.

摘要

多氯联苯(PCBs)和有机氯农药(OCPs)是受限制的化合物,广泛存在于环境中,包括室内空气和住宅灰尘等基质。我们报告了加拿大(23 户家庭)和捷克共和国(20 户家庭)室内空气中和灰尘中的 PCBs 和选定 OCPs 的浓度。室内空气 PCBs 和 OCPs 的浓度比室外高约 10 倍。这两个国家的 PCB 浓度相似,约为 450ng/m,在 PCBs 受到限制之前建造的房屋中浓度更高,并且与每个国家制造或使用的 PCB 混合物的成分一致。所有 OCP 空气浓度在捷克共和国都高于加拿大样本,这表明 DDT 和 HCH 等物质在室内的使用更为普遍。这些数据强调了这些有机氯化合物在室内的持久性,以及即使在新用途被禁止几十年后,它们仍存在于家庭中。这些遗留的持久性有机污染物的室内水平与目前关注的化合物(如溴化阻燃剂和全氟烷基物质)的浓度相似,这表明鉴于对 PCB 和 OCP 毒性的了解,它们值得持续关注。

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