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利用 Parkia speciosa Hassk 豆荚提取物绿色合成 SnO 量子点,评估其抗氧化和光催化性能。

Green synthesis of SnO quantum dots using Parkia speciosa Hassk pods extract for the evaluation of anti-oxidant and photocatalytic properties.

机构信息

Department of Chemistry, National Institute of Technology, Silchar 788010, Assam, India.

Department of Chemistry, National Institute of Technology, Silchar 788010, Assam, India.

出版信息

J Photochem Photobiol B. 2018 Jul;184:44-53. doi: 10.1016/j.jphotobiol.2018.04.041. Epub 2018 May 1.

Abstract

In the present study, microwave heating method was established for the biosynthesis of SnO Quantum dots (QDs) using Parkia speciosa Hassk pods extract. The as-synthesized quantum dots have been characterized by various techniques such as UV, XRD, EDX, TEM, HRTEM, SAED and FTIR spectroscopy. The biosynthesized SnO QDs was employed for the first time as an efficient photocatalyst for the degradation of a food dye, acid yellow 23 dye from aqueous phase under the UV light. Various parameters, such as the effect of catalyst dose, the initial concentration of acid yellow 23 dye (AY23), pH of the solution and irradiation time on the photodegradation process are also studied for efficient and better use of the synthesized SnO QDs as a catalyst. The biosynthesized SnO QDs exhibited excellent photocatalytic performances with degradation efficiency 98% on the degradation of an aqueous solution of AY23 of concentration 5 mg/L with a catalyst dose of 20 mg under UV light within 24 min. The synthesized SnO QDs can be reused up to 5 cycles of photodegradation experiment without losing its stability and efficiency. The biosynthesized SnO QDs also shows a fair activity in the scavenging of 2,2-diphenyl-1-picrylhydrazyl free radical with the IC value of 312.6 ± 0.025 μg/mL.

摘要

在本研究中,采用百香果酸豆荚提取物,通过微波加热法合成了 SnO 量子点 (QD)。通过各种技术对合成的量子点进行了表征,如紫外-可见光谱、X 射线衍射 (XRD)、能谱 (EDX)、透射电子显微镜 (TEM)、高分辨率透射电子显微镜 (HRTEM)、选区电子衍射 (SAED) 和傅里叶变换红外光谱 (FTIR) 等。所合成的 SnO QD 首次被用作高效光催化剂,在紫外光下从水相中降解食品染料酸性黄 23 染料。还研究了各种参数,如催化剂剂量、酸性黄 23 染料 (AY23) 的初始浓度、溶液 pH 值和照射时间对光降解过程的影响,以实现高效、更好地利用所合成的 SnO QD 作为催化剂。所合成的 SnO QD 表现出优异的光催化性能,在浓度为 5mg/L 的 AY23 水溶液中,催化剂剂量为 20mg,在紫外光下 24min 内降解效率达到 98%。所合成的 SnO QD 可在 5 次光降解实验中重复使用,而不会失去其稳定性和效率。所合成的 SnO QD 对 2,2-二苯基-1-苦肼基自由基的清除也表现出相当的活性,IC 值为 312.6±0.025μg/mL。

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