Soochow Institute for Energy and Materials InnovationS, College of Physics, Optoelectronics and Energy, Collaborative Innovation Center of Suzhou Nano Science and Technology, Key Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province, Soochow University, Suzhou, 215006, China.
Polish Academy of Sciences, M. Curie-Sklodowskiej 34, Zabrze, 41-819, Poland.
Adv Mater. 2019 Mar;31(9):e1800715. doi: 10.1002/adma.201800715. Epub 2018 Jun 10.
Modern aberration corrected transmission electron microscopes offer the potential for electron beam sensitive materials, such as graphene, to be examined with low energy electrons to minimize, and even avoid, damage while still affording atomic resolution, and thus providing excellent characterization. Here in this review, the exploits in which the electron beam interactions, which are often considered negative, are explored to usefully drive a wealth of chemistry in and around graphene, importantly, with no other external stimuli. After introducing the technique, this review covers carbon phase reactions between amorphous carbon, graphene, fullerenes, carbon chains, and carbon nanotubes. It then explores different studies with clusters and nanoparticles, followed by coverage of single atom and molecule interactions with graphene, and finally concludes and highlights the anticipated exciting future for electron beam driving chemistry in and around graphene.
现代像差校正透射电子显微镜为电子束敏感材料（如石墨烯）提供了用低能电子进行检查的可能性，以最小化甚至避免损坏，同时仍能实现原子分辨率，从而提供出色的特性。在这篇综述中，我们探讨了电子束相互作用的利用，这些相互作用通常被认为是负面的，但却可以用来在石墨烯内部和周围驱动丰富的化学反应，重要的是，不需要任何其他外部刺激。在介绍该技术之后，本综述涵盖了非晶碳、石墨烯、富勒烯、碳链和碳纳米管之间的碳相反应。然后探讨了与团簇和纳米颗粒的不同研究，接着是单原子和分子与石墨烯的相互作用，最后总结并强调了电子束驱动石墨烯内部和周围化学的令人兴奋的未来。
