Jiang Qi, Zhang Xingwang, You Jingbi
Key Lab of Semiconductor Materials Science, Institute of Semiconductors, Chinese Academy of Sciences, Beijing, 100083, P. R. China.
College of Materials Science and Opto-electronic Technology, University of Chinese Academy of Sciences, Beijing, 100049, P. R. China.
Small. 2018 Jun 25:e1801154. doi: 10.1002/smll.201801154.
The highest power conversion efficiency of perovskite solar cells is beyond 22%. Charge transport layers are found to be critical for device performance and stability. A traditional electron transport layer (ETL), such as TiO , is not very efficient for charge extraction at the interface, especially in planar structure. In addition, the devices using TiO suffer from serious degradation under ultraviolet illumination. SnO owns a better band alignment with the perovskite absorption layer and high electron mobility, which is helpful for electron extraction. In this Review, recent progresses in efficient and stable perovskite solar cells using SnO as ETL are summarized.
钙钛矿太阳能电池的最高功率转换效率超过22%。发现电荷传输层对器件性能和稳定性至关重要。传统的电子传输层(ETL),如TiO,在界面处的电荷提取效率不高,尤其是在平面结构中。此外,使用TiO的器件在紫外光照射下会严重降解。SnO与钙钛矿吸收层具有更好的能带匹配和高电子迁移率,这有助于电子提取。在本综述中,总结了使用SnO作为ETL的高效稳定钙钛矿太阳能电池的最新进展。