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在 SrTiO_{3} 位错处原子级测量挠曲电极化。

Atomic-Scale Measurement of Flexoelectric Polarization at SrTiO_{3} Dislocations.

机构信息

Institute of Engineering Innovation, School of Engineering, The University of Tokyo, Tokyo 113-8656, Japan.

International Center for Quantum Materials, School of Physics, Peking University, Beijing 100871, China.

出版信息

Phys Rev Lett. 2018 Jun 29;120(26):267601. doi: 10.1103/PhysRevLett.120.267601.

Abstract

Owing to the broken translational symmetry at dislocations, a strain gradient naturally exists around the dislocation cores and can significantly influence the electrical and mechanical properties. We use aberration corrected scanning transmission electron microscopy to directly measure the flexoelectric polarization (∼28  μC cm^{-2}) at dislocation cores in SrTiO_{3}. The polarization charges can interact with the nonstoichiometric dislocation cores and thus impact the electrical activities. Our findings can help us to understand the properties of dislocations in perovskite, providing new insights into the design of new devices via defect engineering such as bicrystal fabrication and thin film growth.

摘要

由于位错处的平移对称性被破坏,在其位错核心周围会自然存在应变梯度,这会显著影响材料的电学和力学性能。我们使用相衬校正扫描透射电子显微镜,直接测量了 SrTiO3 中位错核心处的挠曲电极化(∼28 μC cm^{-2})。这些极化电荷会与非化学计量比的位错核心相互作用,从而影响电活性。我们的研究结果有助于理解钙钛矿中的位错性质,为通过双晶制造和薄膜生长等缺陷工程设计新型器件提供了新的思路。

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