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含钼和钨的甲酸盐脱氢酶和甲酰甲硫氨酸脱氢酶：结构、机制和辅因子插入。

Molybdenum- and tungsten-containing formate dehydrogenases and formylmethanofuran dehydrogenases: Structure, mechanism, and cofactor insertion.

机构信息

Department of Biochemistry, University of California, Riverside.

出版信息

Protein Sci. 2019 Jan;28(1):111-122. doi: 10.1002/pro.3498. Epub 2018 Oct 31.

DOI:10.1002/pro.3498
PMID:30120799
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6295890/
Abstract

An overview is provided of the molybdenum- and tungsten-containing enzymes that catalyze the interconversion of formate and CO , focusing on common structural and mechanistic themes, as well as a consideration of the manner in which the mature Mo- or W-containing cofactor is inserted into apoprotein.

摘要

提供了一个概述，介绍了催化甲酸盐和 CO 相互转化的含钼和钨的酶，重点介绍了常见的结构和机制主题，以及考虑了成熟的 Mo 或 W 含辅因子插入到脱辅蛋白中的方式。

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Molybdenum- and tungsten-containing formate dehydrogenases and formylmethanofuran dehydrogenases: Structure, mechanism, and cofactor insertion.含钼和钨的甲酸盐脱氢酶和甲酰甲硫氨酸脱氢酶：结构、机制和辅因子插入。
Protein Sci. 2019 Jan;28(1):111-122. doi: 10.1002/pro.3498. Epub 2018 Oct 31.
2
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本文引用的文献

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Efficient reduction of CO by the molybdenum-containing formate dehydrogenase from ().来自（）的含钼甲酸脱氢酶对CO的高效还原作用。
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Oxidation-State-Dependent Binding Properties of the Active Site in a Mo-Containing Formate Dehydrogenase.氧化态依赖的钼含甲酸脱氢酶活性位点的结合特性。
J Am Chem Soc. 2017 Jul 26;139(29):9927-9936. doi: 10.1021/jacs.7b03958. Epub 2017 Jul 17.
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The methanogenic CO2 reducing-and-fixing enzyme is bifunctional and contains 46 [4Fe-4S] clusters.产甲烷二氧化碳还原固定酶具有双功能，包含 46 个 [4Fe-4S]簇。
Science. 2016 Oct 7;354(6308):114-117. doi: 10.1126/science.aaf9284.
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The physiology and habitat of the last universal common ancestor.最后普遍共同祖先的生理学和栖息地。
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Reduction of Carbon Dioxide by a Molybdenum-Containing Formate Dehydrogenase: A Kinetic and Mechanistic Study.含钼甲酸盐脱氢酶还原二氧化碳：动力学和机理研究。
J Am Chem Soc. 2016 Jul 20;138(28):8834-46. doi: 10.1021/jacs.6b03941. Epub 2016 Jul 7.
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The Molybdenum Active Site of Formate Dehydrogenase Is Capable of Catalyzing C-H Bond Cleavage and Oxygen Atom Transfer Reactions.甲酸脱氢酶的钼活性位点能够催化碳氢键断裂和氧原子转移反应。
Biochemistry. 2016 Apr 26;55(16):2381-9. doi: 10.1021/acs.biochem.6b00002. Epub 2016 Apr 18.
7
Spectroscopic and Kinetic Properties of the Molybdenum-containing, NAD+-dependent Formate Dehydrogenase from Ralstonia eutropha.来自真养产碱杆菌的含钼、依赖NAD⁺的甲酸脱氢酶的光谱和动力学性质
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Sulfido and cysteine ligation changes at the molybdenum cofactor during substrate conversion by formate dehydrogenase (FDH) from Rhodobacter capsulatus.在荚膜红细菌甲酸脱氢酶（FDH）进行底物转化过程中，钼辅因子处的硫代和半胱氨酸连接发生变化。
Inorg Chem. 2015 Apr 6;54(7):3260-71. doi: 10.1021/ic502880y. Epub 2015 Mar 24.
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Sulphur shuttling across a chaperone during molybdenum cofactor maturation.硫原子在钼辅因子成熟过程中穿越伴侣蛋白。
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10
Assembly and catalysis of molybdenum or tungsten-containing formate dehydrogenases from bacteria.细菌中含钼或钨的甲酸脱氢酶的组装与催化作用
Biochim Biophys Acta. 2015 Sep;1854(9):1090-100. doi: 10.1016/j.bbapap.2014.12.006. Epub 2014 Dec 13.