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基于分子内电荷转移的用于乙腈中水分的比色和荧光传感器：D-(π-A)-型吡啶-三氟化硼络合物。

A colorimetric and fluorescent sensor for water in acetonitrile based on intramolecular charge transfer: D-(π-A)-type pyridine-boron trifluoride complex.

机构信息

Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, 1-4-1 Kagamiyama, Higashihiroshima 739-8527, Japan.

出版信息

Chem Commun (Camb). 2018 Sep 6;54(72):10144-10147. doi: 10.1039/c8cc06257a.

DOI:10.1039/c8cc06257a
PMID:30132474
Abstract

A D-(π-A)2-type pyridine-boron trifluoride complex composed of a carbazole skeleton and two pyridine-boron trifluoride units was designed and developed as a colorimetric and fluorescent sensor based on intramolecular charge transfer (ICT) for the detection of water over a wide range from low water content to high water content in solvents.

摘要

一种由咔唑骨架和两个吡啶-三氟化硼单元组成的 D-(π-A)2 型吡啶-三氟化硼配合物，被设计和开发为基于分子内电荷转移（ICT）的比色和荧光传感器，用于在溶剂中从低含水量到高含水量的宽范围内检测水。

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