Centre for Atmospheric Science, Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, UK.
Alphasense Ltd., Sensor Technology House, 300 Avenue West, Skyline 120, Great Notley, Essex CM77 7AA, UK.
Sensors (Basel). 2018 Aug 24;18(9):2790. doi: 10.3390/s18092790.
There is increasing concern about the health impacts of ambient Particulate Matter (PM) exposure. Traditional monitoring networks, because of their sparseness, cannot provide sufficient spatial-temporal measurements characteristic of ambient PM. Recent studies have shown portable low-cost devices (e.g., optical particle counters, OPCs) can help address this issue; however, their application under ambient conditions can be affected by high relative humidity () conditions. Here, we show how, by exploiting the measured particle size distribution information rather than PM as has been suggested elsewhere, a correction can be derived which not only significantly improves sensor performance but which also retains fundamental information on particle composition. A particle size distribution⁻based correction algorithm, founded on κ -Köhler theory, was developed to account for the influence of on sensor measurements. The application of the correction algorithm, which assumed physically reasonable κ values, resulted in a significant improvement, with the overestimation of PM measurements reduced from a factor of ~5 before correction to 1.05 after correction. We conclude that a correction based on particle size distribution, rather than PM mass, is required to properly account for effects and enable low cost optical PM sensors to provide reliable ambient PM measurements.
人们越来越关注环境颗粒物 (PM) 暴露对健康的影响。传统的监测网络由于其稀疏性,无法提供环境 PM 特有的充分时空测量。最近的研究表明,便携式低成本设备(例如,光学粒子计数器,OPC)可以帮助解决这个问题;然而,它们在环境条件下的应用可能会受到高相对湿度(RH)条件的影响。在这里,我们展示了如何通过利用测量的颗粒尺寸分布信息而不是像其他地方所建议的那样利用 PM,可以得出一种修正方法,这种方法不仅可以显著提高传感器的性能,而且还可以保留有关颗粒组成的基本信息。开发了一种基于颗粒尺寸分布的修正算法,该算法基于κ-Köhler 理论,以解释 RH 对传感器测量的影响。应用修正算法,假设物理上合理的 κ 值,结果得到了显著改善,修正前 PM 测量的高估因子从 5 倍左右降低到 1.05 倍。我们得出结论,需要基于颗粒尺寸分布而不是 PM 质量进行修正,以正确考虑 RH 效应,并使低成本的光学 PM 传感器能够提供可靠的环境 PM 测量。