Abe Sofie, Joos Jonas J, Martin Lisa Idj, Hens Zeger, Smet Philippe F
Department of Inorganic and Physical Chemistry, Ghent University, Gent, Belgium.
Department of Solid State Sciences, LumiLab, Ghent University, Gent, Belgium.
Light Sci Appl. 2017 Jun 2;6(6):e16271. doi: 10.1038/lsa.2016.271. eCollection 2017 Jun.
Quantum dots are ideally suited for color conversion in light emitting diodes owing to their spectral tunability, high conversion efficiency and narrow emission bands. These properties are particularly important for display backlights; the highly saturated colors generated by quantum dots justify their higher production cost. Here, we demonstrate the benefits of a hybrid remote phosphor approach that combines a green-emitting europium-doped phosphor with red-emitting CdSe/CdS core/shell quantum dots. Different stacking geometries, including mixed and separate layers of both materials, are studied at the macroscopic and microscopic levels to identify the configuration that achieves maximum device efficiency while minimizing material usage. The influence of reabsorption, optical outcoupling and refractive index-matching between the layers is evaluated in detail with respect to device efficiency and cost. From the findings of this study, general guidelines are derived to optimize both the cost and efficiency of CdSe/CdS and other (potentially cadmium-free) quantum dot systems. When reabsorption of the green and/or red emission is significant compared to the absorption strength for the blue emission of the pumping light emitting diode, the hybrid remote phosphor approach becomes beneficial.
量子点因其光谱可调性、高转换效率和窄发射带,非常适合用于发光二极管中的颜色转换。这些特性对于显示器背光源尤为重要;量子点产生的高饱和颜色证明了其较高的生产成本是合理的。在此,我们展示了一种混合远程荧光粉方法的优势,该方法将发射绿色光的铕掺杂荧光粉与发射红色光的CdSe/CdS核壳量子点相结合。在宏观和微观层面研究了不同的堆叠几何结构,包括两种材料的混合层和分离层,以确定在最小化材料使用的同时实现最大器件效率的配置。详细评估了层间的再吸收、光输出耦合和折射率匹配对器件效率和成本的影响。根据本研究的结果,得出了优化CdSe/CdS和其他(可能无镉)量子点系统的成本和效率的一般指导原则。当绿色和/或红色发射的再吸收与泵浦发光二极管蓝色发射的吸收强度相比显著时,混合远程荧光粉方法就变得有益。