Department of Nano-Mechanics, Korea Institute of Machinery & Materials (KIMM), 156, Gajeongbuk-ro, Yuseong-gu, Daejeon, 34103, Republic of Korea.
Department of Nanomechatronics, University of Science and Technology (UST), Daejeon, 34113, Republic of Korea.
Sci Rep. 2023 Mar 24;13(1):4836. doi: 10.1038/s41598-023-31945-6.
In this paper, we successfully fabricated color conversion layers (CCLs) for full-color-mico-LED display using a perovskite quantum dot (PQD)/siloxane composite by ligand exchanged PQD with silane composite followed by surface activation by an addition of halide-anion containing salt. Due to this surface activation, it was possible to construct the PQD surface with a silane ligand using a non-polar organic solvent that does not damage the PQD. As a result, the ligand-exchanged PQD with a silane compound exhibited high dispersibility in the siloxane matrix and excellent atmospheric stability due to sol-gel condensation. Based on highly ambient stable PQD/siloxane composite based CCLs, full-color micro-LED display has a 1 mm pixel pitch, about 25.4 pixels per inch (PPI) resolution was achieved. In addition, due to the thin thickness of the black matrix to prevent blue light interference, the possibility of a flexible display that can be operated without damage even with a bending radius of 5 mm was demonstrated.
在本文中,我们成功地使用钙钛矿量子点(PQD)/硅氧烷复合材料通过配体交换 PQD 与硅烷复合材料,然后通过添加含卤阴离子盐进行表面活化,为全彩色微型 LED 显示器制造了颜色转换层(CCL)。由于这种表面活化,有可能使用不会损坏 PQD 的非极性有机溶剂在 PQD 表面构建硅烷配体。结果,用硅烷化合物交换的 PQD 在硅氧烷基质中表现出高分散性和由于溶胶-凝胶缩合而具有优异的大气稳定性。基于高度稳定的基于 PQD/硅氧烷复合材料的 CCL,全彩色微型 LED 显示器具有 1mm 的像素间距,实现了约 25.4 像素每英寸(PPI)的分辨率。此外,由于黑色矩阵的厚度很薄,可以防止蓝光干扰,因此即使弯曲半径为 5mm,也可以展示出无需损坏即可操作的柔性显示器的可能性。