Molecular Catalysis, Catalysis Research Center and Department of Chemistry, Technische Universität München, Lichtenbergstr. 4, 85747 Garching bei München, Germany.
Dalton Trans. 2018 Oct 2;47(38):13281-13313. doi: 10.1039/c8dt02346h.
Due to the high emissions of CO2 and the related environmental impact, the chemical transformation of CO2 to useful industrially relevant products or their precursor is of significant interest. Recycling CO2 as a building block for the synthesis of chemicals may not only reduce further emission by at least replacing oil-derived feedstocks, but also provide the advantages of CO2 as an inexpensive, non-toxic and easily available substrate. The catalytic conversion of CO2 into small, useful molecules such as carbonates, methyl amines, methanol, formic acid, etc. by molecular catalysts is an interesting topic that has strongly developed in recent years. This review provides an overview of current scientific progress in the activation and conversion of carbon dioxide with industrially and scientifically relevant substrates using molecular catalysts. Metal-based catalysts are presented in the first part of the review whereas metal-free systems are described in the second part.
由于 CO2 的高排放及其相关的环境影响，将 CO2 化学转化为有用的工业相关产品或其前体引起了人们的极大关注。将 CO2 作为合成化学品的构建块进行回收，不仅可以通过至少替代石油衍生原料来减少进一步的排放，而且还可以提供 CO2 作为廉价、无毒且易于获得的底物的优势。近年来，通过分子催化剂将 CO2 转化为小分子、有用的分子，如碳酸盐、甲基胺、甲醇、甲酸等，已成为一个非常有趣的课题。本综述概述了近年来利用分子催化剂对工业和科学相关底物的二氧化碳的活化和转化方面的最新科学进展。综述的第一部分介绍了基于金属的催化剂，第二部分描述了无金属体系。
