钡催化的 C-OH/P-H 脱水交叉偶联反应构建 C-P 键。
Barium-catalyzed C-OH/P-H dehydrative cross-coupling for C-P bond construction.
机构信息
School of Chemistry and Molecular Engineering, Institute of Advanced Synthesis, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech University, Nanjing 211816, P. R. China.
出版信息
Chem Commun (Camb). 2018 Oct 2;54(79):11132-11135. doi: 10.1039/c8cc06530f.
PMID:30225501
Abstract
A barium-catalyzed C-OH/P-H dehydrative cross-coupling protocol for the construction of C-P bonds was developed. This reaction was performed in an environmentally benign manner with water as the only by-product. A variety of allylic phosphorus compounds can be isolated in good to excellent yields.
摘要
发展了一种由钡催化的 C-OH/P-H 脱水交叉偶联反应构建 C-P 键的方法。该反应在环境友好的条件下进行，以水为唯一的副产物。各种烯丙基磷化合物可以以良好到优秀的收率分离得到。
相似文献
1
Barium-catalyzed C-OH/P-H dehydrative cross-coupling for C-P bond construction.钡催化的 C-OH/P-H 脱水交叉偶联反应构建 C-P 键。
Chem Commun (Camb). 2018 Oct 2;54(79):11132-11135. doi: 10.1039/c8cc06530f.
2
Dehydrative Allylation of Alkenyl sp C-H Bonds.烯基sp C-H键的脱水烯丙基化反应
Org Lett. 2021 Jun 4;23(11):4368-4373. doi: 10.1021/acs.orglett.1c01309. Epub 2021 May 14.
3
Recent approaches for C-C bond formation via direct dehydrative coupling strategies.近期通过直接脱水偶联策略构建 C-C 键的方法。
Chem Soc Rev. 2013 Feb 7;42(3):1121-46. doi: 10.1039/c2cs35397k.
4
Palladium-catalyzed dehydrative allylation of hypophosphorous acid with allylic alcohols.钯催化次磷酸与烯丙醇的脱水烯丙基化反应。
Org Lett. 2006 Aug 31;8(18):4169-71. doi: 10.1021/ol061828e.
5
Dehydrative Cross-Coupling for C-N Bond Construction under Transition-Metal-Free Conditions.无过渡金属条件下用于构建C-N键的脱水交叉偶联反应
Org Lett. 2022 Aug 12;24(31):5657-5662. doi: 10.1021/acs.orglett.2c01902. Epub 2022 Jul 28.
6
Reciprocal-Activation Strategy for Allylic Sulfination with Unactivated Allylic Alcohols.非活化烯丙醇的烯丙基砜化的相互激活策略。
Org Lett. 2020 Jun 19;22(12):4893-4897. doi: 10.1021/acs.orglett.0c01747. Epub 2020 Jun 4.
7
Transition-metal-catalyzed C-N bond forming reactions using organic azides as the nitrogen source: a journey for the mild and versatile C-H amination.过渡金属催化的以有机叠氮化物为氮源的 C-N 键形成反应：温和且多功能的 C-H 氨化反应的探索之旅。
Acc Chem Res. 2015 Apr 21;48(4):1040-52. doi: 10.1021/acs.accounts.5b00020. Epub 2015 Mar 30.
8
Copper-catalyzed dehydrogenative cross-coupling reaction between allylic C-H bonds and α-C-H bonds of ketones or aldehydes.铜催化的烯丙基C-H键与酮或醛的α-C-H键之间的脱氢交叉偶联反应。
Chemistry. 2014 May 26;20(22):6618-21. doi: 10.1002/chem.201402114. Epub 2014 Apr 22.
9
Alkaline-Earth Metal Catalyzed Dehydrative Allylic Alkylation.
Org Lett. 2020 Jan 3;22(1):31-35. doi: 10.1021/acs.orglett.9b03730. Epub 2019 Dec 16.
10
Direct dehydrative cross-coupling of tautomerizable heterocycles with alkynes via Pd/Cu-catalyzed phosphonium coupling.钯/铜催化磷翁偶联促进互变异构杂环化合物与炔烃的直接脱水交叉偶联。
Chem Commun (Camb). 2010 Feb 28;46(8):1347-9. doi: 10.1039/b917777a. Epub 2010 Jan 11.
Zotero 插件