Sarycheva Asia, Polemi Alessia, Liu Yuqiao, Dandekar Kapil, Anasori Babak, Gogotsi Yury
Department of Materials Science and Engineering and A.J. Drexel Nanomaterials Institute, Drexel University, Philadelphia, PA 19104, USA.
Department of Electrical and Computer Engineering, Drexel University, Philadelphia, PA 19104, USA.
Sci Adv. 2018 Sep 21;4(9):eaau0920. doi: 10.1126/sciadv.aau0920. eCollection 2018 Sep.
With the development of the Internet of Things (IoT), the demand for thin and wearable electronic devices is growing quickly. The essential part of the IoT is communication between devices, which requires radio-frequency (RF) antennas. Metals are widely used for antennas; however, their bulkiness limits the fabrication of thin, lightweight, and flexible antennas. Recently, nanomaterials such as graphene, carbon nanotubes, and conductive polymers came into play. However, poor conductivity limits their use. We show RF devices for wireless communication based on metallic two-dimensional (2D) titanium carbide (MXene) prepared by a single-step spray coating. We fabricated a ~100-nm-thick translucent MXene antenna with a reflection coefficient of less than -10 dB. By increasing the antenna thickness to 8 μm, we achieved a reflection coefficient of -65 dB. We also fabricated a 1-μm-thick MXene RF identification device tag reaching a reading distance of 8 m at 860 MHz. Our finding shows that 2D titanium carbide MXene operates below the skin depth of copper or other metals as well as offers an opportunity to produce transparent antennas. Being the most conductive, as well as water-dispersible, among solution-processed 2D materials, MXenes open new avenues for manufacturing various classes of RF and other portable, flexible, and wearable electronic devices.
随着物联网(IoT)的发展,对轻薄且可穿戴电子设备的需求迅速增长。物联网的核心部分是设备之间的通信,这需要射频(RF)天线。金属被广泛用于天线;然而,其笨重性限制了薄型、轻质且灵活的天线的制造。最近,诸如石墨烯、碳纳米管和导电聚合物等纳米材料开始发挥作用。然而,导电性差限制了它们的使用。我们展示了基于通过单步喷涂制备的金属二维(2D)碳化钛(MXene)的用于无线通信的射频设备。我们制造了一种反射系数小于 -10 dB的约100纳米厚的半透明MXene天线。通过将天线厚度增加到8μm,我们实现了 -65 dB的反射系数。我们还制造了一种1μm厚的MXene射频识别设备标签,在860 MHz时读取距离达到8 m。我们的发现表明,二维碳化钛MXene在低于铜或其他金属的趋肤深度下运行,并且提供了制造透明天线的机会。作为溶液处理的二维材料中导电性最高且可水分散的材料,MXenes为制造各类射频及其他便携式、灵活且可穿戴电子设备开辟了新途径。