• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

使用生物废弃物衍生的多相钴催化剂对末端烯烃和内烯烃进行氢化反应。

Hydrogenation of terminal and internal olefins using a biowaste-derived heterogeneous cobalt catalyst.

作者信息

Scharnagl Florian Korbinian, Hertrich Maximilian Franz, Ferretti Francesco, Kreyenschulte Carsten, Lund Henrik, Jackstell Ralf, Beller Matthias

机构信息

Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein Straße 29a, D-18059 Rostock, Germany.

出版信息

Sci Adv. 2018 Sep 21;4(9):eaau1248. doi: 10.1126/sciadv.aau1248. eCollection 2018 Sep.

DOI:10.1126/sciadv.aau1248
PMID:30255152
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6155093/
Abstract

Hydrogenation of olefins is achieved using biowaste-derived cobalt chitosan catalysts. Characterization of the optimal Co@Chitosan-700 by STEM (scanning transmission electron microscopy), EELS (electron energy loss spectroscopy), PXRD (powder x-ray diffraction), and elemental analysis revealed the formation of a distinctive magnetic composite material with high metallic Co content. The general performance of this catalyst is demonstrated in the hydrogenation of 50 olefins including terminal, internal, and functionalized derivatives, as well as renewables. Using this nonnoble metal composite, hydrogenation of terminal C==C double bonds occurs under very mild and benign conditions (water or methanol, 40° to 60°C). The utility of Co@Chitosan-700 is showcased for efficient hydrogenation of the industrially relevant examples diisobutene, fatty acids, and their triglycerides. Because of the magnetic behavior of this material and water as solvent, product separation and recycling of the catalyst are straightforward.

摘要

使用生物废弃物衍生的钴壳聚糖催化剂实现烯烃的氢化。通过扫描透射电子显微镜（STEM）、电子能量损失谱（EELS）、粉末X射线衍射（PXRD）和元素分析对最佳的Co@壳聚糖-700进行表征，结果表明形成了一种具有高金属钴含量的独特磁性复合材料。该催化剂的一般性能在50种烯烃的氢化反应中得到了证明，这些烯烃包括末端烯烃、内烯烃、官能化衍生物以及可再生烯烃。使用这种非贵金属复合材料，末端C==C双键的氢化反应在非常温和且良性的条件下（水或甲醇，40°至60°C）即可发生。Co@壳聚糖-700在工业相关实例二异丁烯、脂肪酸及其甘油三酯的高效氢化反应中的实用性得到了展示。由于该材料的磁性以及水作为溶剂，产物分离和催化剂的循环利用都很简单。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/51fd/6155093/39c04f4e13dc/aau1248-S3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/51fd/6155093/6c7ad4052573/aau1248-S1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/51fd/6155093/7ee4f7cd9b2b/aau1248-F1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/51fd/6155093/7ff7855a08f0/aau1248-S2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/51fd/6155093/39c04f4e13dc/aau1248-S3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/51fd/6155093/6c7ad4052573/aau1248-S1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/51fd/6155093/7ee4f7cd9b2b/aau1248-F1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/51fd/6155093/7ff7855a08f0/aau1248-S2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/51fd/6155093/39c04f4e13dc/aau1248-S3.jpg

相似文献

1
Hydrogenation of terminal and internal olefins using a biowaste-derived heterogeneous cobalt catalyst.使用生物废弃物衍生的多相钴催化剂对末端烯烃和内烯烃进行氢化反应。
Sci Adv. 2018 Sep 21;4(9):eaau1248. doi: 10.1126/sciadv.aau1248. eCollection 2018 Sep.
2
X-ray absorption spectroscopy of Mn/Co/TiO2 Fischer-Tropsch catalysts: relationships between preparation method, molecular structure, and catalyst performance.Mn/Co/TiO₂费托合成催化剂的X射线吸收光谱：制备方法、分子结构与催化剂性能之间的关系
J Phys Chem B. 2006 May 4;110(17):8626-39. doi: 10.1021/jp0565958.
3
A State-of-the-Art Heterogeneous Catalyst for Efficient and General Nitrile Hydrogenation.一种用于高效通用腈氢化反应的先进多相催化剂。
Chemistry. 2020 Dec 1;26(67):15589-15595. doi: 10.1002/chem.202001866. Epub 2020 Sep 24.
4
Co-Based Catalysts Derived from Layered-Double-Hydroxide Nanosheets for the Photothermal Production of Light Olefins.基于层状双氢氧化物纳米片的钴基催化剂用于光热生产低碳烯烃。
Adv Mater. 2018 Aug;30(31):e1800527. doi: 10.1002/adma.201800527. Epub 2018 Jun 5.
5
Convenient and mild epoxidation of alkenes using heterogeneous cobalt oxide catalysts.使用多相钴氧化物催化剂方便温和地环氧化烯烃。
Angew Chem Int Ed Engl. 2014 Apr 22;53(17):4359-63. doi: 10.1002/anie.201310420. Epub 2014 Mar 18.
6
Industrial Ziegler-type hydrogenation catalysts made from Co(neodecanoate)2 or Ni(2-ethylhexanoate)2 and AlEt3: evidence for nanoclusters and sub-nanocluster or larger Ziegler-nanocluster based catalysis.由 Co(正癸酸酯)2 或 Ni(异辛酸酯)2 和 AlEt3 制成的工业齐格勒型氢化催化剂：纳米簇和亚纳米簇或更大的齐格勒-纳米簇催化的证据。
Langmuir. 2011 May 17;27(10):6279-94. doi: 10.1021/la200053f. Epub 2011 Apr 11.
7
Iridium Ziegler-type hydrogenation catalysts made from [(1,5-COD)Ir(mu-O2C8H15)](2) and AlEt3: spectroscopic and kinetic evidence for the Ir(n) species present and for nanoparticles as the fastest catalyst.[(1,5-COD)Ir(mu-O2C8H15)](2)和 AlEt3 制备的铱 Ziegler 型加氢催化剂：存在 Ir(n)物种和纳米颗粒作为最快催化剂的光谱和动力学证据。
Inorg Chem. 2010 Sep 6;49(17):8131-47. doi: 10.1021/ic101237c.
8
Development of a General and Selective Nanostructured Cobalt Catalyst for the Hydrogenation of Benzofurans, Indoles and Benzothiophenes.用于苯并呋喃、吲哚和苯并噻吩加氢的通用和选择性纳米结构钴催化剂的开发。
Angew Chem Int Ed Engl. 2023 Mar 1;62(10):e202215699. doi: 10.1002/anie.202215699. Epub 2023 Jan 26.
9
Understanding the mechanisms of cobalt-catalyzed hydrogenation and dehydrogenation reactions.理解钴催化加氢和脱氢反应的机理。
J Am Chem Soc. 2013 Jun 12;135(23):8668-81. doi: 10.1021/ja402679a. Epub 2013 May 29.
10
Methoxycarbonylation of diisobutylene into methyl isononanoate catalyzed by cobalt complexes dispersed by poly(ionic liquids).聚（离子液体）分散的钴配合物催化二异丁烯甲氧基羰基化合成甲基异壬酸酯
RSC Adv. 2024 Aug 28;14(35):25703-25711. doi: 10.1039/d4ra04745a. eCollection 2024 Aug 12.

引用本文的文献

1
Trigonal Planar Bis(carbene)Cu(I) Complexes Enable Divergent H Activation with HO for Accelerated Olefin Hydrogenation.三角平面双（卡宾）铜（I）配合物可实现与HO的不同H活化，以加速烯烃氢化。
Angew Chem Int Ed Engl. 2025 Aug 11;64(33):e202510627. doi: 10.1002/anie.202510627. Epub 2025 Jun 29.
2
A general and robust Ni-based nanocatalyst for selective hydrogenation reactions at low temperature and pressure.一种用于低温低压下选择性加氢反应的通用且稳健的镍基纳米催化剂。
Sci Adv. 2023 Dec;9(48):eadj8225. doi: 10.1126/sciadv.adj8225. Epub 2023 Dec 1.
3
Water oxidation couples to electrocatalytic hydrogenation of carbonyl compounds and unsaturated carbon-carbon bonds by nickel.

本文引用的文献

1
Single-atom dispersed Co-N-C catalyst: structure identification and performance for hydrogenative coupling of nitroarenes.单原子分散的Co-N-C催化剂：结构鉴定及硝基芳烃氢化偶联性能
Chem Sci. 2016 Sep 1;7(9):5758-5764. doi: 10.1039/c6sc02105k. Epub 2016 Jun 13.
2
Magnetic Nanomaterials: Chemical Design, Synthesis, and Potential Applications.磁性纳米材料：化学设计、合成及潜在应用。
Acc Chem Res. 2018 Feb 20;51(2):404-413. doi: 10.1021/acs.accounts.7b00407. Epub 2018 Feb 7.
3
Regio- and Chemoselective Hydrogenation of Dienes to Monoenes Governed by a Well-Structured Bimetallic Surface.
水氧化与镍催化的羰基化合物和不饱和碳-碳键的电催化氢化反应相耦合。
Sci Rep. 2022 Nov 19;12(1):19968. doi: 10.1038/s41598-022-23777-7.
4
Designing a Multifunctional Catalyst for the Direct Production of Gasoline-Range Isoparaffins from CO.设计一种用于由一氧化碳直接生产汽油馏分异链烷烃的多功能催化剂。
JACS Au. 2021 Oct 6;1(11):1961-1974. doi: 10.1021/jacsau.1c00317. eCollection 2021 Nov 22.
5
Ambient Hydrogenation and Deuteration of Alkenes Using a Nanostructured Ni-Core-Shell Catalyst.使用纳米结构镍核壳催化剂对烯烃进行环境氢化和氘化反应。
Angew Chem Int Ed Engl. 2021 Aug 16;60(34):18591-18598. doi: 10.1002/anie.202105492. Epub 2021 Jun 24.
6
Heterogeneous Olefin Hydrogenation Enabled by a Highly-Reduced Nickel(-II) Catalyst Precursor.高度还原的镍（II）催化剂前体制备的烯烃加氢多相化。
Chemistry. 2020 May 15;26(28):6113-6117. doi: 10.1002/chem.201905537. Epub 2020 Apr 24.
7
Colloidal Palladium Nanoparticles for Selective Hydrogenation of Styrene Derivatives with Reactive Functional Groups.用于具有反应性官能团的苯乙烯衍生物选择性氢化的胶体钯纳米颗粒
ACS Omega. 2019 Nov 26;4(24):20819-20828. doi: 10.1021/acsomega.9b03335. eCollection 2019 Dec 10.
区域和化学选择性双烯加氢为单烯受规整双金属表面控制。
J Am Chem Soc. 2017 Dec 20;139(50):18231-18239. doi: 10.1021/jacs.7b08792. Epub 2017 Dec 7.
4
MOF-derived cobalt nanoparticles catalyze a general synthesis of amines.基于多器官衰竭（MOF）的钴纳米粒子催化了一种胺类的通用合成方法。
Science. 2017 Oct 20;358(6361):326-332. doi: 10.1126/science.aan6245. Epub 2017 Sep 21.
5
Divalent Silicon-Assisted Activation of Dihydrogen in a Bis(N-heterocyclic silylene)xanthene Nickel(0) Complex for Efficient Catalytic Hydrogenation of Olefins.双价硅辅助双（N-杂环硅亚基）呫吨镍(0)配合物中二氢化反应的活化及其在烯烃高效催化加氢反应中的应用。
J Am Chem Soc. 2017 Sep 27;139(38):13499-13506. doi: 10.1021/jacs.7b07167. Epub 2017 Sep 12.
6
Recent Advances in Asymmetric Hydrogenation of Tetrasubstituted Olefins.四取代烯烃不对称氢化的最新进展。
J Am Chem Soc. 2017 Aug 30;139(34):11630-11641. doi: 10.1021/jacs.7b07188. Epub 2017 Aug 21.
7
Biomass-Derived Catalysts for Selective Hydrogenation of Nitroarenes.生物质衍生催化剂用于硝基芳烃的选择性加氢。
ChemSusChem. 2017 Aug 10;10(15):3035-3039. doi: 10.1002/cssc.201700796. Epub 2017 Jul 17.
8
A Biomass-Derived Non-Noble Cobalt Catalyst for Selective Hydrodehalogenation of Alkyl and (Hetero)Aryl Halides.一种生物质衍生的非贵金属钴催化剂，用于选择性还原烷基和（杂）芳基卤化物。
Angew Chem Int Ed Engl. 2017 Sep 4;56(37):11242-11247. doi: 10.1002/anie.201702478. Epub 2017 Jun 30.
9
Alkene Metalates as Hydrogenation Catalysts.作为氢化催化剂的烯烃金属盐。
Chemistry. 2017 Mar 2;23(13):3139-3151. doi: 10.1002/chem.201605222. Epub 2017 Feb 6.
10
Single-Site Cobalt Catalysts at New Zr8(μ2-O)8(μ2-OH)4 Metal-Organic Framework Nodes for Highly Active Hydrogenation of Alkenes, Imines, Carbonyls, and Heterocycles.单原子钴催化剂在新型 Zr8(μ2-O)8(μ2-OH)4 金属有机骨架节点上用于烯烃、亚胺、羰基和杂环化合物的高效加氢反应。
J Am Chem Soc. 2016 Sep 21;138(37):12234-42. doi: 10.1021/jacs.6b06759. Epub 2016 Sep 6.