通过共晶中间体进行的机械化学碳-碳键形成。
Mechanochemical carbon-carbon bond formation that proceeds via a cocrystal intermediate.
机构信息
Ruđer Bošković Institute, Bijenička c. 54, 10000 Zagreb, Croatia.
出版信息
Chem Commun (Camb). 2018 Nov 22;54(94):13216-13219. doi: 10.1039/c8cc07853j.
PMID:30403231
Abstract
We report the first cocrystal as an intermediate in a solid-state organic reaction wherein molecules of barbituric acid and vanillin assume a favorable orientation for the subsequent Knoevenagel condensation.
摘要
我们报告了首例固态有机反应中的共晶中间体，其中巴比妥酸和香草醛分子采取了有利于随后的Knoevenagel 缩合反应的取向。
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