Department of Electrical Engineering, Indian Institute of Technology, Hyderabad, 502285, India.
Nanotechnology. 2019 Jan 18;30(3):035402. doi: 10.1088/1361-6528/aaed78.
While all reports on supercapacitors are based on electrodes that are fabricated either using expensive, complex fabrication techniques or multiple steps based synthesis routes, the current work is the first report of one-step hydrothermally grown MoS on pencil graphite electrode (PGE) for ultra-high performance supercapacitor application. Field emission scanning electron microscope images revealed MoS micro-flower like structure containing interwoven nanosheets whereas chemical characterizations data confirmed the successful growth of few layered (>4 layers) MoS on PGE. The performance of the electrode was optimized using various grades of pencil, and it was found that the areal capacitance of the MoS grown on 1H PGE(7178.8 mF cm) was about 3.4 and 4.1 folds greater than those of the MoS grown on 2B, 6H PGE at the same current density respectively. This low cost, binder-free MoS based PGE paves a novel way towards the advancement of affordable electrodes for energy storage-conversion and bioanalytical applications.
虽然所有关于超级电容器的报告都是基于使用昂贵、复杂的制造技术或基于多步合成路线制造的电极,但目前的工作是首次报道在铅笔石墨电极 (PGE) 上一步水热生长 MoS 用于超高性能超级电容器应用。场发射扫描电子显微镜图像显示 MoS 具有相互交织的纳米片的微花状结构,而化学特性数据证实了 PGE 上成功生长了几层(>4 层)MoS。通过使用各种等级的铅笔优化了电极的性能,发现生长在 1H PGE(7178.8 mF cm)上的 MoS 的比电容(7178.8 mF cm)比生长在 2B 和 6H PGE 上的 MoS 分别高出约 3.4 倍和 4.1 倍,在相同的电流密度下。这种低成本、无粘合剂的基于 MoS 的 PGE 为储能转换和生物分析应用的经济实惠电极的发展铺平了新的道路。