Suppr超能文献

连续流动合成的支持性催化剂。

Supported Catalysts for Continuous Flow Synthesis.

机构信息

Department of Pharmacy, Drug Sciences, University of Bari "A. Moro", FLAME-Lab-Flow Chemistry and Microreactor Technology Laboratory, Via E. Orabona 4, 70125, Bari, Italy.

出版信息

Top Curr Chem (Cham). 2018 Nov 24;376(6):46. doi: 10.1007/s41061-018-0225-0.

Abstract

Flow chemistry and heterogenous catalysis hold incredible potential from a sustainability point of view and from a green perspective. In fact, if heterogenous catalysts are required by the chemical industry for their efficiency, on the other hand, heterogenous flow catalysis would allow performing greener and more efficient chemistry at an industrial level. In the context of sustainable flow chemistry, in this chapter we report and discuss selected examples recently published in the specialized literature on the use of supported organic and organometallic catalysts for continuous flow synthesis. The use in chemo- and stereoselective synthesis, as well as versatility and robustness of the newly developed supported catalysts are discussed.

摘要

从可持续发展的角度和绿色环保的角度来看,流动化学和多相催化具有巨大的潜力。事实上,如果说对于工业生产效率来说多相催化剂是化学工业所必需的,那么多相流动催化将允许在工业层面上进行更绿色、更高效的化学实验。在可持续流动化学的背景下,在本章中,我们报告并讨论了最近在专门文献中发表的关于使用负载型有机和有机金属催化剂进行连续流合成的一些例子。讨论了新开发的负载型催化剂在化学和立体选择性合成中的应用、多功能性和稳定性。

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