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使用火山灰土壤,通过批量法和离心法测定农药土壤吸附参数的比较。

Comparison of soil sorption parameters of pesticides measured by batch and centrifugation methods using an andosol.

作者信息

Motoki Yutaka, Iwafune Takashi, Seike Nobuyasu, Inao Keiya, Namiki Sayuri

机构信息

Food and Agricultural Materials Inspection Center, Agricultural Chemicals Inspection Station, 2-772 Suzuki-cho, Kodaira, Tokyo 187-0011, Japan.

Food Safety Commission Secretariat of Japan, Akasaka Park Bld. 22nd F. 5-2-20 Akasaka, Minato-ku, Tokyo 107-6122, Japan.

出版信息

J Pestic Sci. 2018 Nov 20;43(4):277-282. doi: 10.1584/jpestics.D18-015.

DOI:10.1584/jpestics.D18-015
PMID:30479550
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6240779/
Abstract

We compared the soil sorption coefficient ( ) measured by batch and centrifugation methods using a Japanese andosol and ten pesticides. Although the values measured by both methods increased with time, those obtained the batch method tended to be higher during the test period. The difference in values between the two methods affected pesticide concentrations estimated in the soil solution, and the results estimated using values obtained the batch method underestimated the observed trends.

摘要

我们使用一种日本火山灰土壤和十种农药,比较了通过批量法和离心法测得的土壤吸附系数( )。尽管两种方法测得的 值均随时间增加,但在测试期间,通过批量法获得的值往往更高。两种方法测得的 值差异影响了土壤溶液中估计的农药浓度,并且使用批量法获得的 值估计的结果低估了观测趋势。

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A simulation model (PostPLANT-Soil) for predicting pesticide concentrations in succeeding leafy vegetables: I. Validation with experimental data in a Japanese Andosol field.用于预测后续叶菜类蔬菜中农药浓度的模拟模型(PostPLANT-Soil):I. 基于日本安山土田间实验数据的验证
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本文引用的文献

1
Effect of Time-Dependent Sorption on the Dissipation of Water-Extractable Pesticides in Soils.时间依赖性吸附对土壤中可提取水农药消散的影响。
J Agric Food Chem. 2016 Jun 8;64(22):4478-86. doi: 10.1021/acs.jafc.6b01028. Epub 2016 May 27.
2
Changes in pesticide adsorption with time at high soil to solution ratios.在高土液比条件下农药吸附随时间的变化
Chemosphere. 2007 Jul;68(7):1335-43. doi: 10.1016/j.chemosphere.2007.01.024. Epub 2007 Feb 22.
3
Comparison of two methods for estimation of soil sorption for imidacloprid and carbofuran.两种估算吡虫啉和呋喃丹土壤吸附量方法的比较。
Chemosphere. 2005 Sep;60(9):1325-31. doi: 10.1016/j.chemosphere.2005.01.075.
4
Alternative calibration approaches to compensate the effect of co-extracted matrix components in liquid chromatography-electrospray ionisation tandem mass spectrometry analysis of pesticide residues in plant materials.在植物材料中农药残留的液相色谱-电喷雾电离串联质谱分析中,用于补偿共提取基质成分影响的替代校准方法。
J Chromatogr A. 2002 Oct 11;973(1-2):13-26. doi: 10.1016/s0021-9673(02)01196-2.
5
A partition-limited model for the plant uptake of organic contaminants from soil and water.一种用于植物从土壤和水中吸收有机污染物的分区限制模型。
Environ Sci Technol. 2001 Apr 1;35(7):1437-44. doi: 10.1021/es0017561.